Formation of a palladium(II) complex of 2-(2-pyridinylmethyleneamino)-2′-hydroxy-1,1′-binaphthyl with novel Cσ-coordination and its theoretical investigation

被引:15
|
作者
Xu, LJ
Shi, Q
Li, XS
Jia, X
Huang, X
Wang, RH
Zhou, ZY
Lin, ZY
Chan, ASC [1 ]
机构
[1] Hong Kong Polytech Univ, Inst Mol Technol Drug Discovery & Synth, Open Lab Chirotechnol, Hong Kong, Hong Kong, Peoples R China
[2] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China
[3] Hong Kong Univ Sci & Technol, Dept Chem, Hong Kong, Hong Kong, Peoples R China
关键词
D O I
10.1039/b303477a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Complexation of the NOBIN-derived Schiff base ligand 1 with Pd(CH3CN)(2)Cl-2 has been observed to result in a novel Pd-C bonding mode and theoretical calculations based on B3LYP density functional theory have been carried out to clarify the reaction mechanism.
引用
收藏
页码:1666 / 1667
页数:2
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