Characterization of BiFeO3 nanopowder obtained by mechanochemical synthesis

Bismuth ferrite nanopowders have been obtained by mechanochemical synthesis. The materials were characterized by high resolution electron microscopy. X-ray diffraction and NIR Raman scattering. The XRD pattern of the powder consists of reflections, characteristic of BiFeO3 perovskite structure. superimposed on broad maxima that can be ascribed to an amorphous/disordered phase. The analysis of the two broad bands at low 20 angle yields mean distances of about 3 and 1.8 angstrom which may be related to Bi-O and Fe-O bonds, respectively. The powder consists of loosely packed grains with a broad distribution of sizes between a few nm and 45 nm. The grains of sizes larger than about 30 nm exhibit well-developed crystalline structure. (c) 2007 Elsevier Ltd. All rights reserved.