The Schiff base′-bis(3-nitrobenzylidene)propane-1,3-diamine

被引:14
作者
Habibi, Mohammad Hossein [1 ]
Mokhtari, Reza
Harrington, Ross W.
Clegg, William
机构
[1] Univ Isfahan, Dept Chem, Catalysis Div, Esfahan 81746, Iran
[2] Newcastle Univ, Sch Nat Sci Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
关键词
D O I
10.1107/S1600536807021940
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The molecule of the title Schiff base compound, C17H16N4O4, has crystallographic twofold rotation symmetry. The nitro and CH = N-C substituents are coplanar with the benzene ring in each half of the molecule. These two planar units are parallel, but extend in opposite directions from the central methylene bridge, so there is no intramolecular pi- stacking. Instead, molecules pack with approximately parallel interleaved benzene rings providing intermolecular pi-stacking, the centroid-to-centroid separation being 3.7196 (18) angstrom.
引用
收藏
页码:O2881 / U2247
页数:8
相关论文
共 8 条
[1]   π-Stacked hydrogen-bonded sheets in N,N′-bis(4-nitrobenzylidene)ethane-1,2-diamine and π-stacked hydrogen-bonded chains in N,N-bis(4-nitrobenzylidene)propane-1,3-diamine [J].
Bomfim, JAS ;
Wardell, JL ;
Low, JN ;
Skakle, JMS ;
Glidewell, C .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 :O53-O56
[2]   An intensity evaluation method:: EVAL-14 [J].
Duisenberg, AJM ;
Kroon-Batenburg, LMJ ;
Schreurs, AMM .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :220-229
[3]   Three-dimensional supramolecular structures in (E,E)-N,N-bis(4-nitro-benzylidene)butane-1,4-diamine and (E,E)-N,N'-bis(4-nitrobenzylidene)hexane-1,6-diamine [J].
Glidewell, C ;
Low, JN ;
Skakle, JMS ;
Wardell, JL .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2006, 62 :O1-O4
[4]   (1RS,2RS)-N,N′-Bis(4-nitrophenylmethylene)cyclohexane-1,2-diamine:: complex sheets built from C-H•••O and C-H•••π(arene) hydrogen bonds [J].
Glidewell, C ;
Low, JN ;
Skakle, JMS ;
Wardell, JL .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 :O551-O554
[5]   N,N′-Bis(2-nitrobenzylidene)ethylenediamine [J].
Li, YG ;
Zhu, HL ;
Chen, XZ ;
Song, Y .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :O4156-O4157
[6]  
Nonius, 1998, COLLECT
[7]  
SHELDRICK GM, 2005, SHELXTL VERSION 6
[8]   N,N′-Bis(4-nitrobenzylidene)ethane-1,2-diamine [J].
Sun, YX ;
You, ZL ;
Zhu, HL .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 :O1707-O1708