One-step and large-scale preparation of TiO2/amorphous carbon composites with excellent visible light photocatalytic properties

被引:4
作者
Sha, Dawei [1 ]
Wang, Jingjing [1 ]
Wu, Xiao [1 ]
Zou, Han [1 ]
Dai, Yu [1 ]
Ren, Jie [1 ]
Chen, Ming [1 ]
Wu, Yanze [1 ]
Yan, Xuehua [1 ,2 ]
机构
[1] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Jiangsu, Peoples R China
[2] Jiangsu Univ, Inst Adv Mat, Zhenjiang 212013, Jiangsu, Peoples R China
来源
RSC ADVANCES | 2016年 / 6卷 / 70期
关键词
MESOPOROUS TIO2; SINGLE-CRYSTALS; NANOPARTICLES; SPECTRUM;
D O I
10.1039/c6ra11250a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Poor visible light response and high electron-hole recombination efficiency of TiO2 are main problems which limit its applications. A facile method was developed to prepare reduced TiO2/amorphous carbon composites with particle sizes of about 10-20 nm, which have good visible light absorption and low band gap energy (1.37 eV). The results show that the composite prepared using 1.5 mmol ascorbic acid at 180 degrees C has good crystallinity, strong visible light absorption and enhanced catalytic activity. The degradation efficiency of the samples for rhodamine B reaches 90% after 100 min under visible light irradiation.
引用
收藏
页码:65607 / 65612
页数:6
相关论文
共 22 条
[1]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[2]   Titanium Dioxide Nanomaterials for Photovoltaic Applications [J].
Bai, Yu ;
Mora-Sero, Ivan ;
De Angelis, Filippo ;
Bisquert, Juan ;
Wang, Peng .
CHEMICAL REVIEWS, 2014, 114 (19) :10095-10130
[3]   Preparation, characterization and visible-light activity of carbon modified TiO2 with two kinds of carbonaceous species [J].
Chen, Chao ;
Long, Mingce ;
Zeng, Hui ;
Cai, Weimin ;
Zhou, Baoxue ;
Zhang, Jingyi ;
Wu, Yahui ;
Ding, Dawei ;
Wu, Deyong .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 314 (1-2) :35-41
[4]   Black titanium dioxide (TiO2) nanomaterials [J].
Chen, Xiaobo ;
Liu, Lei ;
Huang, Fuqiang .
CHEMICAL SOCIETY REVIEWS, 2015, 44 (07) :1861-1885
[5]   Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals [J].
Chen, Xiaobo ;
Liu, Lei ;
Yu, Peter Y. ;
Mao, Samuel S. .
SCIENCE, 2011, 331 (6018) :746-750
[6]   Semiconductor-based Photocatalytic Hydrogen Generation [J].
Chen, Xiaobo ;
Shen, Shaohua ;
Guo, Liejin ;
Mao, Samuel S. .
CHEMICAL REVIEWS, 2010, 110 (11) :6503-6570
[7]   Mesoporous TiO2 single crystals delivering enhanced mobility and optoelectronic device performance [J].
Crossland, Edward J. W. ;
Noel, Nakita ;
Sivaram, Varun ;
Leijtens, Tomas ;
Alexander-Webber, Jack A. ;
Snaith, Henry J. .
NATURE, 2013, 495 (7440) :215-219
[8]   ELECTRON-PARAMAGNETIC-RES SPECTRUM OF TI-2(7+) IN SINGLE-CRYSTALS OF TI6O11 [J].
FAIRHURST, SA ;
INGLIS, AD ;
LEPAGE, Y ;
MORTON, JR ;
PRESTON, KF .
CHEMICAL PHYSICS LETTERS, 1983, 95 (4-5) :444-448
[9]   Facile preparation of micro-mesoporous carbon-doped TiO2 photocatalysts with anatase crystalline walls under template-free condition [J].
Gu, De-en ;
Lu, Yun ;
Yang, Bang-chao ;
Hu, Yong-da .
CHEMICAL COMMUNICATIONS, 2008, (21) :2453-2455
[10]   Electrical property measurements of Cr-N codoped TiO2 epitaxial thin films grown by pulsed laser deposition [J].
Jacimovic, J. ;
Gaal, R. ;
Magrez, A. ;
Forro, L. ;
Regmi, M. ;
Eres, Gyula .
APPLIED PHYSICS LETTERS, 2013, 102 (17)