Synthesis of Enol Esters through Silver-catalyzed or -mediated Hydroacyloxylation of Internal Alkynes

被引：12

作者：

Kikui, Nanae ^{[1
]}

Hinoue, Tomoaki ^{[1
]}

Usuki, Yoshinosuke ^{[1
]}

Satoh, Tetsuya ^{[1
]}

机构：

[1] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, 3-3-138 Sugimoto, Osaka 5588585, Japan

来源：

CHEMISTRY LETTERS | 2018年 / 47卷 / 02期

关键词：

Silver catalyst; Hydroacyloxylation; Internal alkyne; CARBOXYLIC-ACIDS; RUTHENIUM COMPLEXES; VINYL MONOMERS; PHOTOPOLYMERIZATION; HYDROCARBOXYLATION; CYCLIZATION; SYSTEM;

D O I：

10.1246/cl.170986

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The silver-catalyzed hydroacyloxylation of internal alkynes with tertiary alkanoic acids proceeds stereoselectively to produce (Z)-enol esters. alpha, beta-Unsaturated carboxylic acids and benzoic acids also undergo silver-mediated addition toward alkynes effectively.

引用

页码：141 / 143

页数：3

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