Sulphur-doped porous carbon from a thiophene-based twin monomer

被引:53
作者
Boettger-Hiller, Falko [1 ]
Mehner, Alexander [1 ]
Anders, Susann [2 ]
Kroll, Lothar [2 ]
Cox, Gerhard [3 ]
Simon, Frank [4 ]
Spange, Stefan [1 ]
机构
[1] Tech Univ Chemnitz, Dept Polymer Chem, D-09111 Chemnitz, Germany
[2] Tech Univ Chemnitz, Dept Lightweight Struct & Polymer Technol, D-09107 Chemnitz, Germany
[3] BASF SE, D-67056 Ludwigshafen, Germany
[4] IPF Leibniz Inst Polymerforsch Dresden eV, D-01069 Dresden, Germany
关键词
CATIONIC-POLYMERIZATION; NANOCOMPOSITES;
D O I
10.1039/c2cc35112a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Sulphur-doped carbon was synthesized using a thiophene-based twin monomer. While tetra(thiophene-2-ylmethoxy)-silane can be converted into sulphur containing nanocomposites, which lead to microporous sulphur-doped carbon, it is possible to produce additional mesopores by the use of templates. Thus, a variety of sulphur-doped carbon materials with tailored pore texture are available.
引用
收藏
页码:10568 / 10570
页数:3
相关论文
共 18 条
[1]   Nanoscale Tungsten Trioxide Synthesized by In Situ Twin Polymerization [J].
Boettger-Hiller, Falko ;
Lungwitz, Ralf ;
Seifert, Andreas ;
Hietschold, Michael ;
Schlesinger, Maik ;
Mehring, Michael ;
Spange, Stefan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (47) :8878-8881
[2]   Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction [J].
Gong, Kuanping ;
Du, Feng ;
Xia, Zhenhai ;
Durstock, Michael ;
Dai, Liming .
SCIENCE, 2009, 323 (5915) :760-764
[3]   Nanocomposites prepared by twin polymerization of a single-source monomer [J].
Grund, Silke ;
Kempe, Patrick ;
Baumann, Gisela ;
Seifert, Andreas ;
Spange, Stefan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (04) :628-632
[4]   A Modular Approach for the Synthesis of Nanostructured Hybrid Materials with Tailored Properties: The Simultaneous Twin Polymerization [J].
Loeschner, Tina ;
Mehner, Alexander ;
Grund, Silke ;
Seifert, Andreas ;
Pohlers, Andreas ;
Lange, Arno ;
Cox, Gerhard ;
Haehnle, Hans-Joachim ;
Spange, Stefan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (13) :3258-3261
[5]   Synthesis of Nanosized TiO2 by Cationic Polymerization of (μ4-oxido)-hexakis(μ-furfuryloxo)-octakis(furfuryloxo)-tetra-titanium [J].
Mehner, Alexander ;
Rueffer, Tobias ;
Lang, Heinrich ;
Pohlers, Andreas ;
Hoyer, Walter ;
Spange, Stefan .
ADVANCED MATERIALS, 2008, 20 (21) :4113-+
[6]   Microporous sulfur-doped carbon from thienyl-based polymer network precursors [J].
Paraknowitsch, Jens Peter ;
Thomas, Arne ;
Schmidt, Johannes .
CHEMICAL COMMUNICATIONS, 2011, 47 (29) :8283-8285
[7]   The effect of oxidation on the surface chemistry of sulfur-containing carbons and their arsine adsorption capacity [J].
Petit, Camille ;
Peterson, Gregory W. ;
Mahle, John ;
Bandosz, Teresa J. .
CARBON, 2010, 48 (06) :1779-1787
[8]   Enhancement in Dibenzothiophene Reactive Adsorption from Liquid Fuel via Incorporation of Sulfur Heteroatoms into the Nanoporous Carbon Matrix [J].
Seredych, Mykola ;
Khine, Monmon ;
Bandosz, Teresa J. .
CHEMSUSCHEM, 2011, 4 (01) :139-147
[9]   Methanesulfonic Acid/SiO2 as an Efficient Combination for the Synthesis of 2-Substituted Aromatic and Aliphatic Benzothiazoles from Carboxylic Acids [J].
Sharghi, Hashem ;
Asemani, Omid .
SYNTHETIC COMMUNICATIONS, 2009, 39 (05) :860-867
[10]   Silica surface modification by cationic polymerization and carbenium intermediates [J].
Spange, S .
PROGRESS IN POLYMER SCIENCE, 2000, 25 (06) :781-849