2-{(E)-[(2Z)-(3-Chloro-1-methyl-2,2-dioxo-3,4-dihydro-1H-2,1-benzothiazin-4-ylidene)hydrazinylidene]methyl}phenol

被引:0
作者
Shafiq, Muhammad [1 ]
Khan, Islam Ullah [1 ]
Zia-ur-Rehman, Muhammad [2 ]
Arshad, Muhammad Nadeem [3 ]
Asiri, Abdullah M. [4 ,5 ]
机构
[1] Govt Coll Univ, Dept Chem, Materials Chem Lab, Lahore 54000, Pakistan
[2] Appl Chem Res Ctr, Lahore 54600, Pakistan
[3] Gujarat Univ, Dept Chem, Gujrat 50781, Pakistan
[4] King Abdulaziz Univ, Fac Sci, Ctr Excellence Adv Mat Res, Jeddah, Saudi Arabia
[5] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah, Saudi Arabia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷
关键词
data-to-parameter ratio = 18.0; mean σ(C-C) = 0.006 Å; R factor = 0.073; single-crystal X-ray study; T = 296 K; wR factor = 0.211;
D O I
10.1107/S1600536811055978
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C16H14ClN3O3S, the thiazine ring adopts a sofa (half-chair) conformation, with an r.m.s. deviation from the mean plane of 0.23 angstrom. The S atom and S-bonded C atom exhibit the maximum deviations from the thiazine mean plane [-0.3976 (12) and 0.3179 (14) angstrom, respectively]. The conformations around the double bonds in the R2C=N-N=CHR unit are Z and E. An intramolecular O-H center dot center dot center dot N hydrogen bond with the hydroxy group as donor generates an S(6) ring motif. In the crystal, pairs of weak C-H center dot center dot center dot O interactions connect the molecules, forming inversion dimers.
引用
收藏
页码:O307 / U1883
页数:10
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