Insight into the effect of crystalline structure on the oxygen reduction reaction activities of one-dimensional MnO2

被引:25
作者
Yang, Jingdong [1 ]
Wang, Jinxing [1 ]
Ma, Shiwen [1 ]
Ke, Bin [1 ]
Yu, Le [1 ]
Zeng, Wen [1 ]
Li, Yanqiong [2 ]
Wang, Jinfeng [1 ]
机构
[1] Chongqing Univ, Coll Mat Sci & Engn, Chongqing 400030, Peoples R China
[2] Chongqing Univ Arts & Sci, Sch Elect & Elect Engn, Chongqing 400030, Peoples R China
基金
国家重点研发计划;
关键词
Manganese dioxide; One-dimension nanostructure; Crystalline structure; Oxygen reduction reaction; AIR BATTERIES; EFFICIENT ELECTROCATALYST; ORR ACTIVITY; NANOPARTICLES; ALPHA-MNO2; DEPOSITION; CATALYST; OXIDE;
D O I
10.1016/j.physe.2018.07.032
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
To investigate the morphology and crystalline structure effect on the oxygen reduction reaction (ORR) electrocatalytic, in this work, alpha-MnO2 nanowires, alpha-MnO2 nanorods, beta-MnO2 nanowires and beta-MnO2 nanorods have been successfully synthesized via a hydrothermal process, and their microstructures and electrocatalytic activities were investigated for the ORR. Among the four different types of one-dimension (1D) MnO2, the alpha-MnO2 nanowires exhibited significantly larger electrocatalytic property than the others, which may contribute to the special crystalline structure and larger specific surface area.
引用
收藏
页码:191 / 197
页数:7
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