Enantiopure Metal-Organic Framework Thin Films: Oriented SURMOF Growth and Enantioselective Adsorption

被引：178
|
作者：
Liu, Bo [2 ]
Shekhah, Osama [1 ]
Arslan, Hasan K. [1 ]
Liu, Jinxuan [1 ]
Woell, Christof [1 ]
Fischer, Roland A. [2 ]
机构：
[1] Karlsruhe Inst Technol KIT, Inst Funct Interfaces IFG, D-76344 Karlsruhe, Germany
[2] Ruhr Univ Bochum, Chair Inorgan Chem Organometall & Mat Chem 2, D-44870 Bochum, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 03期
关键词：
enantioselective adsorption; enantiopure metal-organic frameworks; quartz crystal microbalance; surface chemistry; thin films; SELF-ASSEMBLED MONOLAYERS; MOLECULAR-DYNAMICS SIMULATIONS; BY-STEP ROUTE; SORPTION PROPERTIES; CRYSTAL; SEPARATION; DIFFUSION; NUCLEATION; CHEMISTRY; STORAGE;
D O I：
10.1002/anie.201104240
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Stuck on you: Preferred (110) and (001) orientation of enantiopure [{Zn 2((+)cam) 2(dabco)} n] ((+)cam=(1R,3S)-(+)- camphoric acid, dabco=1,4-diazabicyclo(2.2.2)octane) thin films can be controlled by carboxylate and pyridyl groups on self-assembled monolayers (SAMs). With a quartz crystal microbalance, the enantioselective adsorption of enantiomeric hexanediol pairs by enantiopure surface-attached metal-organic frameworks (SURMOF) [Zn 2((±)cam) 2(dabco)] pairs can be demonstrated (see picture). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：807 / 810
页数：4
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