Enantiopure Metal-Organic Framework Thin Films: Oriented SURMOF Growth and Enantioselective Adsorption

被引：181

作者：

Liu, Bo ^{[2
]}

Shekhah, Osama ^{[1
]}

Arslan, Hasan K. ^{[1
]}

Liu, Jinxuan ^{[1
]}

Woell, Christof ^{[1
]}

Fischer, Roland A. ^{[2
]}

机构：

[1] Karlsruhe Inst Technol KIT, Inst Funct Interfaces IFG, D-76344 Karlsruhe, Germany

[2] Ruhr Univ Bochum, Chair Inorgan Chem Organometall & Mat Chem 2, D-44870 Bochum, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 03期

关键词：

enantioselective adsorption; enantiopure metal-organic frameworks; quartz crystal microbalance; surface chemistry; thin films; SELF-ASSEMBLED MONOLAYERS; MOLECULAR-DYNAMICS SIMULATIONS; BY-STEP ROUTE; SORPTION PROPERTIES; CRYSTAL; SEPARATION; DIFFUSION; NUCLEATION; CHEMISTRY; STORAGE;

D O I：

10.1002/anie.201104240

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stuck on you: Preferred (110) and (001) orientation of enantiopure [{Zn 2((+)cam) 2(dabco)} n] ((+)cam=(1R,3S)-(+)- camphoric acid, dabco=1,4-diazabicyclo(2.2.2)octane) thin films can be controlled by carboxylate and pyridyl groups on self-assembled monolayers (SAMs). With a quartz crystal microbalance, the enantioselective adsorption of enantiomeric hexanediol pairs by enantiopure surface-attached metal-organic frameworks (SURMOF) [Zn 2((±)cam) 2(dabco)] pairs can be demonstrated (see picture). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：807 / 810

页数：4

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