Using light and a molecular switch to 'lock' and 'unlock' the Diels-Alder reaction

被引：38

作者：

Erno, Zach ^{[1
]}

Asadirad, Amir Mahmoud ^{[1
]}

Lemieux, Vincent ^{[1
]}

Branda, Neil R. ^{[1
]}

机构：

[1] Simon Fraser Univ, Dept Chem, LABS 4D, Burnaby, BC V5A 1S6, Canada

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 14期

基金：

加拿大自然科学与工程研究理事会;

关键词：

NANOPARTICLES; PHOTOCHROMISM;

D O I：

10.1039/c2ob06908c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Light is used to 'gate' the Diels-Alder reaction using a photoresponsive dithienylfuran backbone and turn the reversibility of the Diels-Alder reaction 'off' and 'on' at 100 degrees C. These features make the reported system an excellent candidate for developing the next generation of self-healing polymers and photothermal drug delivery vehicles.

引用

页码：2787 / 2792

页数：6

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