A tetranuclear copper complex, [Cu4(μ3-OH)2(μ2-OH)2(phen)4(H2O)2](NO3)4•2H2O

被引：7

作者：

Cui, CP ^{[1
]}

Dai, JC ^{[1
]}

Wu, LM ^{[1
]}

Du, WX ^{[1
]}

Wu, XT ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536801006018

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title compound, diaquadi-mu (3)-hydroxo-di-(mu)2--hydroxo-tetraphenanthrolinetetracopper(II) tetranitrate dihydrate, [Cu-4(OH)(4)(C10H8N2)(4)(H2O)(2)]-(NO3)(4). 2H(2)O, was determined by single-crystal X-ray diffraction. The tetranuclear copper structure has a chair form and each copper has a tetragonal pyramidal coordination geometry. The compound was synthesized by the hydro(solvo)thermal method and there is a fluorescence peak at 450 nm.

引用

页码：M198 / M200

页数：3

共 5 条

[1] CARLIN RL, 1969, TRANSIT METAL CHEM, V5, P51
[2] Trinuclear N,N-bridged copper(II) complexes involving a Cu3OH core:: [Cu3(μ3-OH)L3A(H2O)2]A•(H2O)x {L=3-acetylamino-1,2,4-triazolate;: a = CF3SO3, NO3, ClO4; x = 0, 2} synthesis, X-ray structures, spectroscopy, and magnetic properties
Ferrer, S
Haasnoot, JG
Reedijk, J
Müller, E
Cingi, MB
Lanfranchi, M
Lanfredi, AMM
Ribas, J
[J]. INORGANIC CHEMISTRY, 2000, 39 (09) : 1859 - 1867
[3] Countercomplementarity and strong ferromagnetic coupling in a linear mixed μ-acetato, μ-hydroxo trinuclear copper(II) complex.: Synthesis, structure, magnetic properties, EPR, and theoretical studies
Gutierrez, L
Alzuet, G
Real, JA
Cano, J
Borrás, J
Castiñeiras, A
[J]. INORGANIC CHEMISTRY, 2000, 39 (16) : 3608 - 3614
[4] Sheldrick G.M., 1996, SADABS VERSION 2008
[5] SHELDRICK GM, 1997, SHELXS97 SHELXL97 SH

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