A tetranuclear copper complex, [Cu4(μ3-OH)2(μ2-OH)2(phen)4(H2O)2](NO3)4•2H2O

被引：7
|
作者：
Cui, CP [1 ]
Dai, JC [1 ]
Wu, LM [1 ]
Du, WX [1 ]
Wu, XT [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词：
D O I：
10.1107/S1600536801006018
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title compound, diaquadi-mu (3)-hydroxo-di-(mu)2--hydroxo-tetraphenanthrolinetetracopper(II) tetranitrate dihydrate, [Cu-4(OH)(4)(C10H8N2)(4)(H2O)(2)]-(NO3)(4). 2H(2)O, was determined by single-crystal X-ray diffraction. The tetranuclear copper structure has a chair form and each copper has a tetragonal pyramidal coordination geometry. The compound was synthesized by the hydro(solvo)thermal method and there is a fluorescence peak at 450 nm.
引用
收藏
页码：M198 / M200
页数：3
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