Synthesis of biaryls by intramolecular radical transfer in phosphinates

被引：44

作者：

Clive, DLJ ^{[1
]}

Kang, SZ ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 66卷 / 18期

关键词：

D O I：

10.1021/jo010371d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phosphinates 20a-35a give biaryls 20b-35b on heating with stannanes in the presence of AIBN. The process involves a radical ipso substitution on the migrating aryl ring.

引用

页码：6083 / 6091

页数：9

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