Ion Exchange to Capture Iron after Real Effluent Treatment by Fenton's Process

被引:6
作者
Domingues, Eva [1 ]
Fernandes, Eryk [1 ]
Vaz, Telma [1 ]
Gomes, Joao [1 ]
Castro-Silva, Sergio [2 ]
Martins, Rui C. [1 ]
Quinta-Ferreira, Rosa [1 ]
Ferreira, Licinio M. [1 ]
机构
[1] Univ Coimbra, Fac Sci & Technol, CIEPQPF Chem Engn Proc & Forest Prod Res Ctr, Dept Chem Engn, Rua Silvio Lima, Coimbra, Portugal
[2] Adventech Adv Environm Technol, Rua Fundoes 151, Sao Joao Da Madeira, Portugal
关键词
fenton process; iron sludge; strong acid cation exchange; olive oil extraction; AQUEOUS-SOLUTION; WASTE-WATER; REMOVAL; ADSORPTION; PARAMETERS; INDUSTRIAL; ZEOLITE; RESIN; PB2+; DYE;
D O I
10.3390/w14050706
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The main drawback of Fenton ' s process is the formation of ferric sludge. In this work, ion exchange (IE) appears as a complement to the Fenton process, allowing, on the one hand, to remove the iron excess present in the sludge, as well as reduce the COD of the real olive oil industry extraction wastewater (OOIEW) from the Fenton process. The Fenton process uses iron (II) sulfate as catalyst, therefore concentrations of iron up to 2 g L-1 could be present in the treated OOIEW. The iron and COD adsorption equilibrium behavior has been modelized by Langmuir, Freundlich and Temkin isotherms. Moreover, the resin efficiency was tested in a continuous fixed-bed column. It was concluded that the resin maintains iron adsorption capacity over at least three reuse cycles. Overall Fenton's process followed by ion exchange seems to be a promising approach for the treatment of cumbersome industrial wastewaters.
引用
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页数:14
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