Gold(I)-catalysed cascade reactions in the synthesis of 2,3-fused indole derivatives

被引：24
作者：
Gimeno, Ana [1 ]
Rodriguez-Gimeno, Alejandra [1 ]
Cuenca, Ana B. [1 ]
Ramirez de Arellano, Carmen [1 ]
Medio-Simon, Mercedes [1 ]
Asensio, Gregorio [1 ]
机构：
[1] Univ Valencia, Dept Quim Organ, E-46100 Burjassot, Valencia, Spain
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 62期
关键词：
NONREARRANGED MONOTERPENOID UNIT; ACTIVE CARBAZOLE ALKALOIDS; GOLD-CATALYZED SYNTHESIS; ONE-POT SYNTHESIS; INTERMOLECULAR HYDROARYLATION; INTRAMOLECULAR HYDROARYLATION; PALLADIUM(II) COMPLEXES; UNACTIVATED ALKENES; CYCLIZATION; ACTIVATION;
D O I：
10.1039/c5cc04606h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A gold(I)-catalysed hydroaminative/arylative cascade for the efficient synthesis of a variety of indole-fused skeletons has been developed. Factors controlling the catalyst loading required in these transformations involving 1,3-unsubstituted indole intermediates have been revealed, allowing isolation of an unprecedented 1,3-dimetallated 3H-indole gold complex characterized by X-ray diffraction.
引用
收藏
页码：12384 / 12387
页数：4
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