A novel ZnS nanosheets-based triboelectric nanogenerator and its applications in sensing, self-powered electronics, and digital systems

The development of triboelectric nanogenerators (TENGs) based on inexpensive inorganic materials has attracted significant attention to envisage next-generation self-powered electronic devices and sensors. In this research work, the fabrication of a triboelectric nanogenerator (TENG) based on ZnS nanosheets arrays was investigated for the first time. This TENG was fabricated with ZnS nanosheets films, polydimethylsiloxane (PDMS) as active tribo-layers. The originality of this work lies in the choice of materials; pure ZnS nanosheets and PDMS-Al cover foils. By hand excitation force, the developed TENG (5 x 5 cm(2)) produced an output voltage and a short-circuit current of similar to 8 V and similar to 7.12 mu A respectively. In addition, the present TENG with pure ZnS nanosheets on Al substrate produced an output voltage almost twice than TENG that involved only Al substrate. In this current study, introducing ZnS nanosheets on Al substrate increased the surface area and roughness, resulting in improved performance. The study of TENG parameters confirms that the TENG (10 x 10 cm(2)) with 2 cm spacing between tribo layers, applied force frequency of similar to 4-5 Hz were optimum to obtain the maximum output voltage of similar to 33 V. The high stability of TENG was confirmed by testing TENG response over 1000 cycles. Further, TENG was used to power portable electronic devices such as a digital watch, thermometer, calculator, and 64 LEDs when coupled to a capacitor. Finally, TENG was demonstrated for sensing force and pressure, TENG output response was used as a clock pulse for the digital circuits. The proposed TENG is easy to handle, simple and economical, and ZnS-based TENG's performance can be improved using other tribo-materials instead of PDMS.