Collaborative Interaction of Carbon-Carbon Unsaturated Bond Groups with Transition-metal Catalysts for C-H Bond Functionalization

被引：18

作者：

Minami, Yasunori ^{[1
]}

Hiyama, Tamejiro ^{[1
]}

机构：

[1] Chuo Univ, Res & Dev Initiat, Bunkyo Ku, 1-13-27 Kasuga, Tokyo 1128551, Japan

来源：

CHEMISTRY LETTERS | 2018年 / 47卷 / 01期

关键词：

C-H bond activation; Metal catalyst; Carbon-carbon unsaturated bond; ALKYNYL ARYL ETHERS; GAS SHIFT CONDITIONS; SILYLETHYNYL ETHERS; SELECTIVE SYNTHESIS; INTERNAL ALKYNES; ACTIVATION; ANNULATION; CYCLOADDITION; CYCLOCARBONYLATION; CLEAVAGE;

D O I：

10.1246/cl.170795

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkynes, alkenes, and thiophenes are found to behave as a directing group for C-H bond activation by a transition-metal catalyst. This collaborative interaction led to the discovery of not only simple intramolecular cyclizations but also carbon-carbon bond formation or annulation reactions with other reactants involving such unsaturated bond-directing groups. This highlight review discusses the recent progress in this sort of novel synthetic tools.

引用

页码：1 / 8

页数：8

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