Facile hydrothermal synthesis of cobalt manganese oxides spindles and their magnetic properties

被引:21
作者
Wang, Ji-Yu [1 ]
Kuang, Pan-Yong [1 ]
Li, Nan [1 ]
Liu, Zhao-Qing [1 ]
Su, Yu-Zhi [1 ]
Chen, Shuang [2 ]
机构
[1] Guangzhou Univ, Guangzhou Key Lab Environm Funct Mat & Technol, Sch Chem & Chem Engn, Guangzhou 510006, Guangdong, Peoples R China
[2] Guangzhou Inst Railway Technol, Guangzhou 510430, Guangdong, Peoples R China
关键词
Magnetic properties; CoMnO3; Co3O4; Mn2O3; Hydrothermal method; CO3O4; PERFORMANCE; DECOMPOSITION; NANOPARTICLES; FABRICATION; MORPHOLOGY; OXIDATION; CATALYSTS; EXCHANGE; BEHAVIOR;
D O I
10.1016/j.ceramint.2015.03.083
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In the present work, CoMnO3, Co3O4 and Mn2O3 powders were prepared by using a simple hydrothermal method, and the urea and polyvinyl alcohol (PVA) were served as the precipitator and surface active agent, respectively. The CoMnO3 and Mn2O3 exhibit the same spindle-like structure with the size of several micrometers, while the Mn2O3 displays the nanosheet morphology, the as-prepared materials are all high degree of crystallinity. In addition, the magnetic properties discussion indicates that the as-prepared materials exhibit ferromagnetic and antiferromagnetic behaviors at 5 K and 300 K, respectively. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:8670 / 8679
页数:10
相关论文
共 57 条
[1]   A STRUCTURAL PHASE-TRANSITION INDUCED BY AN EXTERNAL MAGNETIC-FIELD [J].
ASAMITSU, A ;
MORITOMO, Y ;
TOMIOKA, Y ;
ARIMA, T ;
TOKURA, Y .
NATURE, 1995, 373 (6513) :407-409
[2]   Convenient and Mild Epoxidation of Alkenes Using Heterogeneous Cobalt Oxide Catalysts** [J].
Banerjee, Debasis ;
Jagadeesh, Rajenahally V. ;
Junge, Kathrin ;
Pohl, Marga-Martina ;
Radnik, Joerg ;
Brueckner, Angelika ;
Beller, Matthias .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (17) :4359-4363
[3]   Surfactant-controlled low-temperature thermal decomposition route to monodispersed phase pure tricobalt tetraoxide nanoparticles [J].
Bhattacharjee, Chira R. ;
Purkayastha, Debraj Dhar ;
Das, Nirmalendu .
MATERIALS LETTERS, 2013, 90 :111-114
[4]   Non-equilibrium effects in the magnetic behavior of Co3O4 nanoparticles [J].
Bisht, Vijay ;
Rajeev, K. P. .
SOLID STATE COMMUNICATIONS, 2011, 151 (18) :1275-1279
[5]  
Blundell S., 2001, MAGNETQISM CONDENSED
[6]   Porous Co3O4 microcubes: hydrothermal synthesis, catalytic and magnetic properties [J].
Cao, Feng ;
Wang, Deqiang ;
Deng, Ruiping ;
Tang, Jinkui ;
Song, Shuyan ;
Lei, Yongqian ;
Wang, Song ;
Su, Shengqun ;
Yang, Xiangguang ;
Zhang, Hongjie .
CRYSTENGCOMM, 2011, 13 (06) :2123-2129
[7]   Biomineralization Strategy to α-Mn2O3 Hierarchical Nanostructures [J].
Cao, Huaqiang ;
Wu, Xiaoming ;
Wang, Guohua ;
Yin, Jiefu ;
Yin, Gui ;
Zhang, Fan ;
Liu, Junkun .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (39) :21109-21115
[8]   Synthesis of Mn2O3 homogeneous core/hollow-shell structures with excellent adsorption performance [J].
Cao, Jie ;
Mao, Qinghe ;
Qian, Yitai .
JOURNAL OF SOLID STATE CHEMISTRY, 2012, 191 :10-14
[9]   Synthesis of Mn2O3 microstructures and their energy storage ability studies [J].
Chen, Shulin ;
Liu, Fan ;
Xiang, Quanjun ;
Feng, Xionghan ;
Qiu, Guohong .
ELECTROCHIMICA ACTA, 2013, 106 :360-371
[10]   Surface strontium enrichment on highly active perovskites for oxygen electrocatalysis in solid oxide fuel cells [J].
Crumlin, Ethan J. ;
Mutoro, Eva ;
Liu, Zhi ;
Grass, Michael E. ;
Biegalski, Michael D. ;
Lee, Yueh-Lin ;
Morgan, Dane ;
Christen, Hans M. ;
Bluhm, Hendrik ;
Shao-Horn, Yang .
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (03) :6081-6088