Mixed transition-metal-lanthanide complexes at higher oxidation states:: Heteronuclear CeIV-MnIV clusters

被引：100
作者：
Tasiopoulos, AJ
O'Brien, TA
Abboud, KA
Christou, G [1 ]
机构：
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
[2] Indiana Univ Purdue Univ, Dept Chem, Indianapolis, IN 46202 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 03期
关键词：
cerium; cluster compounds; lanthanides; magnetic properties; manganese; transition metals;
D O I：
10.1002/anie.200352898
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Wheels within wheels: A new family of mixed cerium(IV)-manganese(IV) clusters has been prepared spanning a range of Ce:Mn ratios from 3:2 to 1:6. The unusual core of the latter CeMn6 complex is shown (Ce green, Mn blue, O red). All the compounds exhibit antiferromagnetic interactions between their constituent MnIV ions.
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收藏
页码：345 / 349
页数：5
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