Characterization of chemically modified carbon black for sorption application

A commercial grade carbon black was chemically modified using mineral acids (either with HNO3 or H2SO4 or mixture) and the sorption performance of the virgin and modified forms were investigated. Chemical modification resulted in the creation of surface acidic functional groups (-COOH, -SO2OH) and was verified by FTIR spectra. This was further verified by TGA analysis revealing higher weight loss characteristics of the modified carbons in comparison to virgin carbon black. Morphological changes were observed from BET surface area measurements and SEM analysis. XRD study revealed the change of graphitic crystallite size as a result of modification. The suspension pH of the materials in deionized water and the point of zero charge (pH(pzc)) in inert electrolyte were determined. The measured values of suspension pH and pHpzc for all the carbons were found to be acidic with more acidic character in the modified carbons. These materials were used as sorbents for the removal of arsenic from aqueous medium and showed excellent adsorption performance. (C) 2007 Elsevier B.V. All rights reserved.