Characterization of chemically modified carbon black for sorption application

被引：60

作者：

Borah, Dipu ^{[1
]}

Satokawa, Shigeo ^{[1
]}

Kato, Shigeru ^{[1
]}

Kojima, Toshinori ^{[1
]}

机构：

[1] Seikei Univ, Dept Mat & Life Sci, Fac Sci & Technol, Musashino, Tokyo 1808633, Japan

来源：

APPLIED SURFACE SCIENCE | 2008年 / 254卷 / 10期

关键词：

carbon black; chemical modification; characterization; suspension pH; point of zero charge; arsenic adsorption;

D O I：

10.1016/j.apsusc.2007.10.053

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A commercial grade carbon black was chemically modified using mineral acids (either with HNO3 or H2SO4 or mixture) and the sorption performance of the virgin and modified forms were investigated. Chemical modification resulted in the creation of surface acidic functional groups (-COOH, -SO2OH) and was verified by FTIR spectra. This was further verified by TGA analysis revealing higher weight loss characteristics of the modified carbons in comparison to virgin carbon black. Morphological changes were observed from BET surface area measurements and SEM analysis. XRD study revealed the change of graphitic crystallite size as a result of modification. The suspension pH of the materials in deionized water and the point of zero charge (pH(pzc)) in inert electrolyte were determined. The measured values of suspension pH and pHpzc for all the carbons were found to be acidic with more acidic character in the modified carbons. These materials were used as sorbents for the removal of arsenic from aqueous medium and showed excellent adsorption performance. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：3049 / 3056

页数：8

共 22 条

[1] Modeling of disorder and X-ray diffraction in coal-based graphitic carbons
Babu, VS
Seehra, MS
[J]. CARBON, 1996, 34 (10) : 1259 - 1265
[2] CARBON IN DIESEL PARTICULATE MATTER - STRUCTURE, MICROWAVE-ABSORPTION, AND OXIDATION
BABU, VS
FARINASH, L
SEEHRA, MS
[J]. JOURNAL OF MATERIALS RESEARCH, 1995, 10 (05) : 1075 - 1078
[3] Bodek I., 1988, ENV INORGANIC CHEM P
[4] BOENING HV, 1982, PLASMA SCI TECHNOLOG
[5] On a theory of the van der Waals adsorption of gases
Brunauer, S
Deming, LS
Deming, WE
Teller, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 : 1723 - 1732
[6] CEBRIAN ME, 1994, ARSENIC ENV 2
[7] STUDY ON OXIDATION MECHANISM OF CARBON-BLACKS BY OZONE IN AQUEOUS-MEDIUM
DONNET, JB
EHRBURGE.P
VOET, A
[J]. CARBON, 1972, 10 (06) : 737 - &
[8] Adsorption enthalpies of sodium dodecyl sulphate onto carbon blacks in the low concentration range
González-García, CM
González-Martín, ML
Denoyel, R
Gallardo-Moreno, AM
Labajos-Broncano, L
Bruque, JM
[J]. CARBON, 2005, 43 (03) : 567 - 572
[9] HESS WM, 1993, CARBON BLACK SCI TEC, pCH6
[10] IHARA T, 1984, J CHEM SOC JAPAN, V10, P1575

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