Preparation of ZnO Nanorods/Graphene Composite Anodes for High-Performance Lithium-Ion Batteries

被引:29
作者
Zhang, Junfan [1 ]
Tan, Taizhe [2 ]
Zhao, Yan [1 ]
Liu, Ning [1 ]
机构
[1] Hebei Univ Technol, Sch Mat Sci & Engn, Tianjin 300130, Peoples R China
[2] GDUT, Synergy Innovat Inst, Heyuan 517000, Peoples R China
基金
中国国家自然科学基金;
关键词
ZnO/graphene composites; anode; lithium-ion battery; ELECTROCHEMICAL PERFORMANCE; DOPED GRAPHENE; HIGH-CAPACITY; NANOPARTICLES; NANOSHEETS; NANOTUBE; HYBRID;
D O I
10.3390/nano8120966
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
ZnO is a promising anode material for lithium-ion batteries (LIBs); however, its practical application is hindered primarily by its large volume variation upon lithiation. To overcome this drawback, we synthesized ZnO/graphene composites using the combination of a simple hydrothermal reaction and spray drying. These composites consisted of well-dispersed ZnO nanorods anchored to graphene. The folded three-dimensional graphene spheres provided a high conductivity, high surface area, and abundant defects. LIB with an anode composed of our novel ZnO/graphene material demonstrated a high initial discharge capacity of 1583 mAh g(-1) at 200 mA g(-1).
引用
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页数:9
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共 29 条
[1]   Synthesis of hierarchical flower-like ZnO nanostructures and their functionalization by Au nanoparticles for improved photocatalytic and high performance Li-ion battery anodes [J].
Ahmad, Mashkoor ;
Shi Yingying ;
Nisar, Amjad ;
Sun, Hongyu ;
Shen, Wanci ;
Wei, Miao ;
Zhu, Jing .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (21) :7723-7729
[2]   Spinel LiMn2O4/reduced graphene oxide hybrid for high rate lithium ion batteries [J].
Bak, Seong-Min ;
Nam, Kyung-Wan ;
Lee, Chang-Wook ;
Kim, Kwang-Heon ;
Jung, Hyun-Chul ;
Yang, Xiao-Qing ;
Kim, Kwang-Bum .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (43) :17309-17315
[3]   Electrochemical performance of ball-milled ZnO-SnO2 systems as anodes in lithium-ion battery [J].
Belliard, F ;
Irvine, JTS .
JOURNAL OF POWER SOURCES, 2001, 97-8 :219-222
[4]   Challenges in the development of advanced Li-ion batteries: a review [J].
Etacheri, Vinodkumar ;
Marom, Rotem ;
Elazari, Ran ;
Salitra, Gregory ;
Aurbach, Doron .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3243-3262
[5]   Graphene - carbon nanotube - Mn3O4 mesoporous nano-alloys as high capacity anodes for lithium-ion batteries [J].
Gangaraju, Deepa ;
Sridhar, Vadahanambi ;
Lee, Inwon ;
Park, Hyun .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 699 :106-111
[6]   Nanostructured 3D Electrode Architectures for High-Rate Li-Ion Batteries [J].
Haag, Jacob M. ;
Pattanaik, Gyanaranjan ;
Durstock, Michael F. .
ADVANCED MATERIALS, 2013, 25 (23) :3238-3243
[7]   Electrochemical performance of activated carbon nanofiber with ZnO nanoparticles for Li-ion battery [J].
Kim, So Yeun ;
Kim, Bo-Hye .
SYNTHETIC METALS, 2015, 210 :386-391
[8]   Hydrothermal self-assembly of hierarchical flower-like ZnO nanospheres with nanosheets and their application in Li-ion batteries [J].
Li, Feng ;
Yang, Linlin ;
Xu, Gang ;
Huang Xiaoqiang ;
Yang, Xin ;
Wei, Xiao ;
Ren, Zhaohui ;
Shen, Ge ;
Han, Gaorong .
JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 577 :663-668
[9]   Synthesis and electrochemical investigation of highly dispersed ZnO nanoparticles as anode material for lithium-ion batteries [J].
Li, Haipeng ;
Wei, Yaqiong ;
Zhang, Yongguang ;
Yin, Fuxing ;
Zhang, Chengwei ;
Wang, Gongkai ;
Bakenov, Zhumabay .
IONICS, 2016, 22 (08) :1387-1393
[10]   In situ sol-gel synthesis of ultrafine ZnO nanocrystals anchored on graphene as anode material for lithium-ion batteries [J].
Li, Haipeng ;
Wei, Yaqiong ;
Zhang, Yongguang ;
Zhang, Chengwei ;
Wang, Gongkai ;
Zhao, Yan ;
Yin, Fuxing ;
Bakenov, Zhumabay .
CERAMICS INTERNATIONAL, 2016, 42 (10) :12371-12377