SYNTHESIS OF HYDROXYMETHYLFURFURAL FROM SUCROSE USING BRONSTED-LEWIS ACIDIC IONIC LIQUID

被引：7

作者：

Yao, Lin ^{[1
]}

Liu, Shiwei ^{[1
]}

Li, Lu ^{[1
]}

Yu, Shitao ^{[1
]}

Liu, Fusheng ^{[1
]}

Song, Zhanqian ^{[1
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao 266042, Peoples R China

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA | 2016年 / 30卷 / 02期

关键词：

Acidic ionic liquid; Sucrose; 5-Hydroxymethylfurfural; Catalysis; CATALYST; FRUCTOSE; DEHYDRATION; CONVERSION; WATER;

D O I：

10.4314/bcse.v30i2.12

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of 5-hydroxymethylfurfural (HMF) from sucrose was investigated in the presence of the Bronsted-Lewis acidic ionic liquids (ILs). It was concluded that IL 1-(3-sulfonic acid)-propyl-3-methylimidazole chlorochrominate [HO3S-(CH2)(3)-mim] Cl-CrCl3 (molar fraction of CrCl3 x = 0.55) had a good catalytic performance with 78.8% yield of HMF. The acid type of IL played a significant role in the reaction. Lewis acid site acted more effectively than its Bronsted counterpart and a synergetic effect of Bronsted and Lewis acid sites enhanced the IL catalytic performance. The reusability of IL was good.

引用

页码：283 / 288

页数：6

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