Conformation of the Linear-Dendritic Block Copolymers of Hyperbranched Polyphenylenegermane and Linear Poly(methylmethacrylate)

被引：5

作者：

Simonova, Maria A. ^{[1
]}

Zamyshlyayeva, Olga G. ^{[2
]}

Simonova, Alexandra A. ^{[2
,3
]}

Filippov, Alexander P. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia

[2] Lobachevski Nizhny Novgorod State Univ, Dept Chem, Nizhnii Novgorod, Russia

[3] St Petersburg State Technol Univ Plant Polymers, Dept Chem Engn, St Petersburg, Russia

来源：

INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION | 2015年 / 20卷 / 03期

关键词：

Solutions; Conformation; Hydrodynamic characteristics; Static and dynamic light scattering; Linear-dendritic block-copolymers; MACROMOLECULES;

D O I：

10.1080/1023666X.2015.989381

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Dilute solutions of linear-dendritic block copolymers of linear poly(methylmethacrylate) with hyperbranched polyphenylenegermane were investigated by light scattering methods. The obtained results were compared with characteristics of functionalized poly(methylmethacrylate) with -Ge(C6F5)(3) terminal groups, linear poly(methylmethacrylate), and hyperbranched polyphenylenegermane. The investigated samples differ by molar masses of the linear components. It was shown that molecules of functionalized poly(methylmethacrylate) in solution have a conformation that is typical for linear polymers in good solvent, while the linear-dendritic polymers in dilute chloroform solution have compact structure and high density in comparison with linear poly(methylmethacrylate).

引用

页码：223 / 230

页数：8