Lanthanide complexes in organic synthesis: Synthesis of ethers from allyl alcohols

被引:0
|
作者
Swamy, SJ [1 ]
Nagaraju, D [1 ]
Suresh, K [1 ]
机构
[1] Kakatiya Univ, Dept Chem, Warangal 506009, Andhra Pradesh, India
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Coordinatively unsaturated lanthanide ions catalyze a wide variety of organic reactions. The hepta coordinated Ln(III) complexes with N,N'-ethylene-bis-(2-aminobenzamide) [EBAB] and N,N'-propylene-bis-(2-aminobenzamide) [PBAB], the [Ln(EBAB)Cl-3] or [Ln(PBAB)Cl-3], catalyze the ether formation reactions from allyl alcohols and different nucleophiles. The overall yields of the products are found to be 70-83%.
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页码:3120 / 3123
页数:4
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