Nanocatalysis: Recent advances and applications in boron chemistry

被引：39
作者：
Zhu, Yinghuai [1 ]
Hosmane, Narayan S. [2 ]
机构：
[1] Inst Chem & Engn Sci, Singapore 627833, Singapore
[2] No Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA
来源：
COORDINATION CHEMISTRY REVIEWS | 2015年 / 293卷
基金：
美国国家科学基金会;
关键词：
Nanocatalysis; Boron chemistry; C-C coupling reaction; Boronic acid; borylation; Isotope exchange; Hydrogen storage; CORE-SHELL NANOPARTICLES; CROSS-COUPLING REACTION; HYDROGEN STORAGE CAPACITY; METAL-ORGANIC FRAMEWORK; HIGH CATALYTIC-ACTIVITY; SITU FACILE SYNTHESIS; C-H ACTIVATION; SODIUM-BOROHYDRIDE; AMMONIA-BORANE; EFFICIENT CATALYSTS;
D O I：
10.1016/j.ccr.2014.10.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Considerable progress has been made in the application of transition metal nanoparticles (NP)-based catalysts in boron chemistry. These offer the advantages of high efficiency and good recyclability. Existing drawbacks need to be addressed before use in industrial applications. This review updates the latest progress in the area of nano-catalysis in boron chemistry, such as catalytic break-down and formation of C-B bonds in arenes (e.g., Suzuki-Miyaura cross-coupling reaction), isotopic exchanges in H-B, B-B and I-B containing molecules, and dehydrogenation of boron compounds. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：357 / 367
页数：11
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