Solvent- and Catalyst-Free Carbon Dioxide Capture and Reduction to Formate with Borohydride Ionic Liquid

被引：37

作者：

Lombardo, Loris ^{[1
,2
]}

Yang, Heena ^{[1
,2
]}

Zhao, Kun ^{[1
,2
]}

Dyson, Paul J. ^{[3
]}

Zuettel, Andreas ^{[1
,2
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, Basic Sci Fac, Rue Ind 17, CH-1951 Sion, Switzerland

[2] Empa Mat Sci & Technol, Ueberlandstr 129, CH-8600 Dubendorf, Switzerland

[3] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, CH-1015 Lausanne, Switzerland

来源：

CHEMSUSCHEM | 2020年 / 13卷 / 08期

关键词：

carbon storage; charge transfer; boron; ionic liquids; waste prevention; CO2; CAPTURE; SODIUM-BOROHYDRIDE; HYDROGEN STORAGE; ADSORPTION; FUTURE; NABH4;

D O I：

10.1002/cssc.201903514

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Cover Feature shows the application of a pyrrolidinium-based ionic liquid with a borohydride anion to simultaneously capture and reduce large amounts of CO2. The ionic liquid cation interacts with CO2, allowing the borohydride to fix and reduce it to tri-formatoborohydride (represented as a pitcher plant that can attract and digest CO2). Formic acid can be collected by adding HCl solution. More information can be found in the Full Paper by L. Lombardo et al.

引用

页码：2025 / 2031

页数：7

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