Next-generation multi-crystalline silicon solar cells: Diamond-wire sawing, nano-texture and high efficiency

被引:117
作者
Cao, Fang
Chen, Kexun
Zhang, Jingjiao
Ye, Xiaoya
Li, Jianjiang
Zou, Shuai
Su, Xiaodong [1 ]
机构
[1] Soochow Univ, Coll Phys Optoelect & Energy, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Photovolta Res Inst, Suzhou 215006, Peoples R China
关键词
Multi-crystalline silicon solar cell; Diamond wire sawing; Nano-texture; Metal-catalyzed chemical etching; Power conversion efficiency; MULTICRYSTALLINE SILICON; FEMTOSECOND LASER;
D O I
10.1016/j.solmat.2015.05.030
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The absence of an effective texturing technique for diamond-wire sawn multi-crystalline silicon (DWS mc-Si) solar cells has hindered commercial upgrading from traditional multi-wire slurry sawn silicon (MWSS mc-Si) solar cells. In this paper, a nano-texture technique has been developed to achieve 18.31% efficient DWS mc-Si solar cells on a pilot production line. Their unique pyramidal nanostructure, which has the most close-packed (111) surface of Si diamond crystal, not only benefits both light-trapping and electric properties but also can effectively remove the saw-marks and amorphous layer of the cells. Therefore, the short-circuit current I-sc of a nano-textured DWS mc-Si solar cell is similar to 324 mA higher than that of a micron-textured one, while its open-circuit voltage 140 does not show an evident decrease with the increase of its surface area. The technique has paved the way for the mass production of DWS mc-Si solar cells by satisfying the exact requirements of the PV industry for high efficiency and low cost. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:132 / 138
页数:7
相关论文
共 28 条
[1]   HF/HNO3 etching of the saw damage [J].
Acker, Joerg ;
Koschwitz, Tim ;
Meinel, Birgit ;
Heinemann, Robert ;
Blocks, Christian .
PROCEEDINGS OF THE 3RD INTERNATIONAL CONFERENCE ON CRYSTALLINE SILICON PHOTOVOLTAICS (SILICONPV 2013), 2013, 38 :223-233
[2]  
Bidiville A., 2009, 24 EUR PHOT SOL EN C
[3]   Metal-assisted chemical etching of silicon in HF-H2O2 [J].
Chartier, C. ;
Bastide, S. ;
Levy-Clement, C. .
ELECTROCHIMICA ACTA, 2008, 53 (17) :5509-5516
[4]   Novel texturing process for diamond-wire-sawn single-crystalline silicon solar cell [J].
Chen, Kexun ;
Liu, Yunyu ;
Wang, Xusheng ;
Zhang, Lingjun ;
Su, Xiaodong .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2015, 133 :148-155
[5]  
CHOULAT P., 2007, 22 EUR PHOT SOL EN C
[6]   Comparison of structure and properties of femtosecond and nanosecond laser-structured silicon [J].
Crouch, CH ;
Carey, JE ;
Warrender, JM ;
Aziz, MJ ;
Mazur, E ;
Génin, FY .
APPLIED PHYSICS LETTERS, 2004, 84 (11) :1850-1852
[8]  
Green MA., 1998, Solar Cells: Operating Principles, Technology and System Applications
[9]   Micro and nano-structuration of silicon by femtosecond laser: Application to silicon photovoltaic cells fabrication [J].
Halbwax, M. ;
Sarnet, T. ;
Delaporte, Ph. ;
Sentis, A. ;
Etienne, H. ;
Torregrosa, F. ;
Vervisch, V. ;
Perichaud, I. ;
Martinuzzi, S. .
THIN SOLID FILMS, 2008, 516 (20) :6791-6795
[10]   Microstructuring of silicon with femtosecond laser pulses [J].
Her, TH ;
Finlay, RJ ;
Wu, C ;
Deliwala, S ;
Mazur, E .
APPLIED PHYSICS LETTERS, 1998, 73 (12) :1673-1675