Aurophilic interactions as a subject of current research: an up-date

被引：1011

作者：

Schmidbaur, Hubert ^{[1
,2
]}

Schier, Annette ^{[1
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany

[2] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21589, Saudi Arabia

来源：

CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 01期

关键词：

CENTER-DOT-AU; CLOSED-SHELL ATTRACTION; RAY CRYSTAL-STRUCTURE; LUMINESCENT GOLD(I)-SILVER(I) CLUSTER; DINUCLEAR GOLD(I) COMPLEXES; SOLID-STATE NMR; PHOTOPHYSICAL PROPERTIES; MOLECULAR-STRUCTURE; METALLOPHILIC ATTRACTION; COORDINATION POLYMERS;

D O I：

10.1039/c1cs15182g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recently accumulated experimental evidence for aurophilic interactions in and between molecular gold(I) compounds and the results of pertinent theoretical calculations are reviewed for the period from 2007 to mid-2011. The influence of the intra- and intermolecular bonding contacts between the closed-shell metal centres, Au-Au, on the molecular and crystal structures, and the consequences of these effects for the chemical and physical properties of gold compounds are summarized for the various classes of mono- and polynuclear systems. The literature survey builds on the contents of previous reviews and relates new experimental and theoretical findings to earlier observations (353 references).

引用

页码：370 / 412

页数：43

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