In(OH)BDC•0.75BDCH2 (BDC = benzenedicarboxylate), a hybrid inorganic-organic vernier structure

被引：204
|
作者：
Anokhina, EV [1 ]
Vougo-Zanda, M [1 ]
Wang, XQ [1 ]
Jacobson, AJ [1 ]
机构：
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 43期
关键词：
D O I：
10.1021/ja055757a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The compound In(OH)BDC·0.75BDCH2 (BDC = benzenedicarboxylate), 1, has been synthesized and characterized by single-crystal X-ray diffraction. The structure comprises two distinct sublattices formed by a covalently linked In(OH)BDC lattice and ordered chains of hydrogen-bonded H2BDC molecules and can be described as a hybrid inorganic coordination polymer-organic vernier structure. Each InO6 octahedron of the octahedral chain has a length of 3.6 Å along the chain axis, whereas each H2BDC molecule has a length of 9.6 Å along the guest column axis. Therefore, a unit of eight InO6 octahedra of the octahedral chain is just in registry with three H2BDC molecules of the guest column giving a repeat unit of 28.76 Å along the channel axis direction. Copyright © 2005 American Chemical Society.
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页码：15000 / 15001
页数：2
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