Metal-Organic Framework Based on an Anthracene Tetracarboxylate Ligand and Cadmium or Cobalt: Synthesis, Structure Analysis, Stability and Magnetic Properties

被引：3

作者：

Aleksovska, Angela ^{[1
]}

Zaake-Hertling, Haldor ^{[1
]}

Loennecke, Peter ^{[1
]}

Schwarze, Benedikt ^{[1
]}

Graesing, Daniel ^{[2
]}

Matysik, Joerg ^{[2
]}

Bloemer, Laura ^{[1
]}

Kersting, Berthold ^{[1
]}

Hey-Hawkins, Evamarie ^{[1
]}

机构：

[1] Univ Leipzig, Fak Chem & Mineral, Inst Anorgan Chem, Johannisallee 29, D-04103 Leipzig, Germany

[2] Univ Leipzig, Fak Chem & Mineral, Inst Analyt Chem, Linnestr 3, D-04103 Leipzig, Germany

来源：

CHEMISTRYSELECT | 2020年 / 5卷 / 22期

关键词：

cobalt; cadmium; metal-organic frameworks; solvothermal synthesis; GAS-STORAGE; SEPARATION;

D O I：

10.1002/slct.202001730

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks, a class of porous polymeric materials, are presenting a development on the interface between molecular coordination chemistry and materials science and are becoming one of the hottest research topics in chemistry. Two new metal-organic frameworks, [M'(2){Co-3(ACTBA)(2)}](n)(1; M'=monocation) and [(NH2Et2)(2){Cd-3(ACTBA)(2)}](n)(2) (H(4)ACTBA=2,6,9,10-tetrakis(p-carboxyphenyl)anthracene), composed of trinuclear Co or Cd moieties connected by anthracene tetracarboxylate ligands are presented here, which are highly stable on removal of solvent inside the pores. The synthesis, X-ray structure analysis, NMR spectroscopy (for2), chemical and thermal stability, and magnetic properties (for1) are discussed.

引用

页码：6537 / 6540

页数：4

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