Metal-Organic Framework Based on an Anthracene Tetracarboxylate Ligand and Cadmium or Cobalt: Synthesis, Structure Analysis, Stability and Magnetic Properties

被引：3

作者：

Aleksovska, Angela ^{[1
]}

Zaake-Hertling, Haldor ^{[1
]}

Loennecke, Peter ^{[1
]}

Schwarze, Benedikt ^{[1
]}

Graesing, Daniel ^{[2
]}

Matysik, Joerg ^{[2
]}

Bloemer, Laura ^{[1
]}

Kersting, Berthold ^{[1
]}

Hey-Hawkins, Evamarie ^{[1
]}

机构：

[1] Univ Leipzig, Fak Chem & Mineral, Inst Anorgan Chem, Johannisallee 29, D-04103 Leipzig, Germany

[2] Univ Leipzig, Fak Chem & Mineral, Inst Analyt Chem, Linnestr 3, D-04103 Leipzig, Germany

来源：

CHEMISTRYSELECT | 2020年 / 5卷 / 22期

关键词：

cobalt; cadmium; metal-organic frameworks; solvothermal synthesis; GAS-STORAGE; SEPARATION;

D O I：

10.1002/slct.202001730

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks, a class of porous polymeric materials, are presenting a development on the interface between molecular coordination chemistry and materials science and are becoming one of the hottest research topics in chemistry. Two new metal-organic frameworks, [M'(2){Co-3(ACTBA)(2)}](n)(1; M'=monocation) and [(NH2Et2)(2){Cd-3(ACTBA)(2)}](n)(2) (H(4)ACTBA=2,6,9,10-tetrakis(p-carboxyphenyl)anthracene), composed of trinuclear Co or Cd moieties connected by anthracene tetracarboxylate ligands are presented here, which are highly stable on removal of solvent inside the pores. The synthesis, X-ray structure analysis, NMR spectroscopy (for2), chemical and thermal stability, and magnetic properties (for1) are discussed.

引用

页码：6537 / 6540

页数：4

共 24 条

[1] Metal-organic framework-derived porous materials for catalysis [J].

Chen, Yu-Zhen ;

Zhang, Rui ;

Jiao, Long ;

Jiang, Hai-Long .

COORDINATION CHEMISTRY REVIEWS, 2018, 362 :1-23

[2] Electronic metal-organic framework sensors [J].

Chidambaram, Arunraj ;

Stylianou, Kyriakos C. .

INORGANIC CHEMISTRY FRONTIERS, 2018, 5 (05) :979-998

[3] Industrial applications of metal-organic frameworks [J].

Czaja, Alexander U. ;

Trukhan, Natalia ;

Mueller, Ulrich .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1284-1293

[4] Three-dimensional copper (II) metal-organic framework with open metal sites and anthracene nucleus for highly selective C2H2/CH4 and C2H2/CO2 gas separation at room temperature [J].

Duan, Xing ;

Cai, Jianfeng ;

Yu, Jiancan ;

Wu, Chuande ;

Cui, Yuanjing ;

Yang, Yu ;

Qian, Guodong .

MICROPOROUS AND MESOPOROUS MATERIALS, 2013, 181 :99-104

[5] Unsymmetrical dinuclear cobalt and nickel trimethylacetate complexes [J].

Fomina, IG ;

Sidorov, AA ;

Aleksandrov, GG ;

Zhilova, VI ;

Ikorskii, VN ;

Novotortsev, VM ;

Eremenko, IL ;

Moiseev, II .

RUSSIAN CHEMICAL BULLETIN, 2004, 53 (01) :118-126

[6] An electron rich porous extended framework as a heterogeneous catalyst for Diels-Alder reactions [J].

Gole, Bappaditya ;

Bar, Arun Kumar ;

Mallick, Arijit ;

Banerjee, Rahul ;

Mukherjee, Partha Sarathi .

CHEMICAL COMMUNICATIONS, 2013, 49 (67) :7439-7441

[7] Metal-organic frameworks as stationary phases for mixed-mode separation applications [J].

Hawes, Chris S. ;

Nolvachai, Yada ;

Kulsing, Chadin ;

Knowles, Gregory P. ;

Chaffee, Alan L. ;

Marriott, Philip J. ;

Batten, Stuart R. ;

Turner, David R. .

CHEMICAL COMMUNICATIONS, 2014, 50 (28) :3735-3737

[8] The role of the counter-ion in metal-organic frameworks' chemistry and applications [J].

He, Huacheng ;

Hashemi, Lida ;

Hu, Mao-Lin ;

Morsali, Ali .

COORDINATION CHEMISTRY REVIEWS, 2018, 376 :319-347

[9]

Hesse M., 2005, SPEKTROSKOPISCHE MET, P258

[10] Luminescent metal-organic frameworks for chemical sensing and explosive detection [J].

Hu, Zhichao ;

Deibert, Benjamin J. ;

Li, Jing .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :5815-5840

← 1 2 3 →