Synthesis and characterization of Li2MxMn4-xO8 (M = Co, Fe) as positive active materials for lithium-ion cells

被引:37
作者
Bonino, F [1 ]
Panero, S [1 ]
Satolli, D [1 ]
Scrosati, B [1 ]
机构
[1] Univ Rome La Sapienza, Dipartimento Chim, I-00185 Rome, Italy
关键词
spinel; lithium intercalation; lithium-ion battery;
D O I
10.1016/S0378-7753(01)00630-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We describe the preparation and the electrochemical properties of Li2MxMn4-xO8, spinel-structured compounds. The results demonstrate that these materials may operate as high-voltage cathodes in new concept lithium-ion batteries. An example of these batteries has been fabricated and successfully tested. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:389 / 392
页数:4
相关论文
共 8 条
  • [1] ARRABITO M, 2000, INT M LITH BATT IMLB
  • [2] LiMn2-xCuxO4 spinels (0.1≤x≤0.5):: A new class of 5 V cathode materials for Li batteries -: I.: Electrochemical, structural, and spectroscopic studies
    Ein-Eli, Y
    Howard, WF
    Lu, SH
    Mukerjee, S
    McBreen, J
    Vaughey, JT
    Thackeray, MM
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (04) : 1238 - 1244
  • [3] LINIVO4 - A 4.8 VOLT ELECTRODE MATERIAL FOR LITHIUM CELLS
    FEY, GTK
    LI, W
    DAHN, JR
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (09) : 2279 - 2282
  • [4] High-voltage lithium cathode materials
    Kawai, H
    Nagata, M
    Tukamoto, H
    West, AR
    [J]. JOURNAL OF POWER SOURCES, 1999, 81 : 67 - 72
  • [5] 5 V lithium cathodes based on spinel solid solutions Li2Co1+XMn3-XO8:-1 ≤ X ≤ 1
    Kawai, H
    Nagata, M
    Kageyama, H
    Tukamoto, H
    West, AR
    [J]. ELECTROCHIMICA ACTA, 1999, 45 (1-2) : 315 - 327
  • [6] Synthesis and characterization of LiCoyNi(1-y)VO4 lithium insertion materials
    Panero, S
    Reale, P
    Bonino, F
    Scrosati, B
    Arrabito, M
    Bodoardo, S
    Mazza, D
    Penazzi, N
    [J]. SOLID STATE IONICS, 2000, 128 (1-4) : 43 - 52
  • [7] TODOROV YM, 1998, P 194 INT M EL SOC B
  • [8] Synthesis and electrochemistry of LiNixMn2-xO4
    Zhong, QM
    Bonakdarpour, A
    Zhang, MJ
    Gao, Y
    Dahn, JR
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (01) : 205 - 213