Liquid density of biofuel mixtures: (Dibutyl ether+1-butanol) system at pressures up to 140 MPa and temperatures from (293.15 to 393.15) K

被引:27
作者
Alaoui, Fatima E. M. [1 ,2 ]
Montero, Eduardo A. [1 ]
Bazile, Jean-Patrick [2 ]
Aguilar, Fernando [1 ]
Boned, Christian [2 ]
机构
[1] Univ Burgos, Dept Ingn Electromecan, Escuela Politecn Super, E-09006 Burgos, Spain
[2] Univ Pau & Pays Adour, Lab Fluides Complexes, Fac Sci & Tech, CNRS,UMR 5150, F-64013 Pau, France
关键词
Dibutyl ether; 1-Butanol; Density; High pressure; Excess volume; Isobaric thermal expansivity; Isothermal compressibility; VOLUMETRIC PROPERTIES; DERIVATIVE PROPERTIES; CALIBRATION; DENSIMETER; 1-PENTANOL; RHO;
D O I
10.1016/j.jct.2011.06.006
中图分类号
O414.1 [热力学];
学科分类号
摘要
This work reports new experimental density data (445 points) for binary mixtures of (dibutyl ether + 1-butanol) over the composition range (five compositions: 0.15 <= dibutyl ether mole fraction x <= 0.85), from (293.15 to 393.15)K (every 20 K). and for 15 pressures from (0.1 to 140) MPa (every 10 MPa). An Anton Paar vibrating tube densimeter, calibrated with an uncertainty of +/- 0.5 kg . m(-3) was used to perform these measurements. The experimental density data were fitted with a Tait-like equation with low standard deviations. Excess volumes have been calculated from the experimental data and fitted by the Redlich-Kister equation. In addition, the isobaric thermal expansivity and the isothermal compressibility have been derived from the Taft-like equation. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1768 / 1774
页数:7
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