Synthesis of azo-conjugated catecholate complexes and their photo- and proton-responses

被引：6

作者：

Nagashima, S ^{[1
]}

Nihei, M ^{[1
]}

Yamada, T ^{[1
]}

Murata, M ^{[1
]}

Kurihara, M ^{[1
]}

Nishihara, H ^{[1
]}

机构：

[1] Univ Tokyo, Sch Sci, Dept Chem, Tokyo 1130033, Japan

来源：

MACROMOLECULAR SYMPOSIA | 2003年 / 204卷

关键词：

charge transfer; crystal structures; electrochemistry; isomerization; photochemistry;

D O I：

10.1002/masy.200351409

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new azo-conjugated catecholate ligand, azocat, and its nickel complexes were synthesized, and their physical and chemical properties were investigated. The complex with one azocat shows no obvious photo-response, whereas the compound with two azocat's causes a little photoisomerization. Both of these novel azo-conjugated catecholate complexes show remarkable proton responses.

引用

页码：93 / 101

页数：9

共 34 条

[1] Synthesis of azo-conjugated metal ladithiolenes and their photo- and proton-responsive isomerization reactions
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