Novel low-molecular-weight organic gels: N,N',N''-tristearyltrimesamide/organic solvent system

被引:123
作者
Yasuda, Y [1 ]
Iishi, E [1 ]
Inada, H [1 ]
Shirota, Y [1 ]
机构
[1] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 565, JAPAN
关键词
D O I
10.1246/cl.1996.575
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel class of low-molecular-weight organic gels has been developed; N,N':N ''-tristearyltrimesamide (TSTA) forms gels with various organic solvents, immobilizing solvent at a low concentration of TSTA. The gels, which form fibrous bundles leading to three-dimensional networks, exhibit well-defined sol-gel transitions. Both intermolecular hydrogen bonding and intermolecular interactions between long alkyl chains are suggested to be responsible for the formation of gels.
引用
收藏
页码:575 / 576
页数:2
相关论文
共 15 条
[1]   LIGHT-SCATTERING OBSERVATION OF SPINODAL LINE IN GELATIN GELS [J].
BOHIDAR, HB ;
JENA, SS .
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (04) :3568-3570
[2]   NONLINEAR SWELLING OF POLYMER GELS [J].
DURNING, CJ ;
MORMAN, KN .
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (05) :4275-4293
[3]   CYCLO(DIPEPTIDE)S AS LOW-MOLECULAR-MASS GELLING AGENTS TO HARDEN ORGANIC FLUIDS [J].
HANABUSA, K ;
MATSUMOTO, Y ;
MIKI, T ;
KOYAMA, T ;
SHIRAI, H .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (11) :1401-1402
[4]   2-COMPONENT, SMALL-MOLECULE GELLING AGENTS [J].
HANABUSA, K ;
MIKI, T ;
TAGUCHI, Y ;
KOYAMA, T ;
SHIRAI, H .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (18) :1382-1384
[5]   SMALL MOLECULAR GELLING AGENTS TO HARDEN ORGANIC LIQUIDS - ALKYLAMIDE OF N-BENZYLOXYCARBONYL-L-VALYL-L-VALINE [J].
HANABUSA, K ;
TANGE, J ;
TAGUCHI, Y ;
KOYAMA, T ;
SHIRAI, H .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (04) :390-392
[6]   VOLUME PHASE-TRANSITION IN A NONIONIC GEL [J].
HIROKAWA, Y ;
TANAKA, T .
JOURNAL OF CHEMICAL PHYSICS, 1984, 81 (12) :6379-6380
[7]   ELECTROCHROMIC DISPLAY DEVICE OF TUNGSTEN TRIOXIDE AND PRUSSIAN-BLUE FILMS USING POLYMER GEL ELECTROLYTE OF METHACRYLATE [J].
INABA, H ;
IWAKU, M ;
NAKASE, K ;
YASUKAWA, H ;
SEO, I ;
OYAMA, N .
ELECTROCHIMICA ACTA, 1995, 40 (02) :227-232
[8]   NOVEL FAMILY OF GELATORS OF ORGANIC FLUIDS AND THE STRUCTURE OF THEIR GELS [J].
LIN, Y ;
KACHAR, B ;
WEISS, RG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (15) :5542-5551
[9]   DESIGN OF NOVEL MESOMORPHIC COMPOUNDS - N,N',N''-TRIALKYL-1,3,5-BENZENETRICARBOXAMIDES [J].
MATSUNAGA, Y ;
MIYAJIMA, N ;
NAKAYASU, Y ;
SAKAI, S ;
YONENAGA, M .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (01) :207-210
[10]   THERMAL AND LIGHT CONTROL OF THE SOL-GEL PHASE-TRANSITION IN CHOLESTEROL-BASED ORGANIC GELS - NOVEL HELICAL AGGREGATION MODES AS DETECTED BY CIRCULAR-DICHROISM AND ELECTRON-MICROSCOPIC OBSERVATION [J].
MURATA, K ;
AOKI, M ;
SUZUKI, T ;
HARADA, T ;
KAWABATA, H ;
KOMORI, T ;
OHSETO, F ;
UEDA, K ;
SHINKAI, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (15) :6664-6676