Synthesis and Antimicrobial Activity of Quaternary Ammonium Silane Coupling Agents

被引：12

作者：

Yoshino, Norio ^{[1
,2
]}

Sugaya, Shigenori ^{[1
]}

Nakamura, Toshimitsu ^{[1
]}

Yamaguchi, Yoh-hei ^{[1
]}

Kondo, Yukishige ^{[1
,2
]}

Kawada, Kazuo ^{[3
]}

Teranaka, Toshio ^{[4
]}

机构：

[1] Tokyo Univ Sci, Fac Engn, Shinjuku Ku, Tokyo 1620826, Japan

[2] Tokyo Univ Sci, Inst Colloid & Interface Sci, Shinjuku Ku, Tokyo 1628601, Japan

[3] Kitasato Univ, Fac Sci, Minami Ku, Kanagawa 2520373, Japan

[4] Kanagawa Dent Coll, Dept Oral Med, Div Restorat Dent, Kanagawa 2388580, Japan

来源：

JOURNAL OF OLEO SCIENCE | 2011年 / 60卷 / 08期

关键词：

silane coupling agents; antimicrobial activity; surface modification; quaternary ammonium salts; minimum inhibitory concentrations; POLYMERIC PHOSPHONIUM SALTS; SURFACE MODIFICATION; FLUOROCARBON CHAIN; ANTIBACTERIAL ACTIVITY; CATIONIC BIOCIDES; COMPOSITES; GLASS;

D O I：

10.5650/jos.60.429

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Fourteen novel silane coupling agents with a quaternary ammonium group introduced into the molecule, [CH2=CHCH2N+(CH3)(CnH2n+1)(CH2)(3)Si(OCH3)(3)]X- (n-X, n=10-18, X=Cl, Br, or I), were synthesized with the aim of using these agents to make material surfaces antimicrobial for a long period of time. Measurements of the minimum inhibitory concentrations (MIC) against 12 kinds of fungi and bacteria revealed that the coupling agent with a C-10 alkyl chain and Cl- or Br- counter-ion (10-Cl or 10-Br) has the highest antimicrobial activity among the n-X agents synthesized, but 14-Cl and 14-Br showed the highest activity on a modified porcelain plate.

引用

页码：429 / 438

页数：10

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