The reaction of CH2(3B1)+N2O studied by time-resolved Fourier transform infrared spectroscopy

被引：6

作者：

Su, HM

Yang, JX

Zhong, JX

Kong, FN ^{[1
]}

机构：

[1] Acad Sinica, Inst Chem, Lab Mol React Dynam, Beijing 100080, Peoples R China

[2] Acad Sinica, Ecoenvironm Sci Res Ctr, Beijing 100085, Peoples R China

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 303卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(99)00154-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction dynamics of methylene radical CH2((X) over tilde(3)B(1)) with N2O was investigated by time-resolved Fourier transform infrared spectroscopy. Pure CH2((X) over tilde(3)B(1)) radical was produced via laser photolysis of ketene at 351 nm. Nascent vibrationally excited products CO, NO and HCN were observed. Five reaction pathways and three possible reaction intermediates are proposed. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：526 / 530

页数：5

共 8 条

[1] REACTIONS OF (CH2)-C-1, CL AND BR IN THE PRESENCE OF NITROUS-OXIDE [J].