Norcorrole:: Observation of the smallest porphyrin variant with a N4 core

被引：88

作者：

Broering, Martin ^{[1
]}

Koehler, Silke ^{[1
]}

Kleeberg, Christian ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 30期

关键词：

bidipyrrin; iron; macrocycles; norcorrole; porphyrinoids;

D O I：

10.1002/anie.200801196

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A newborn member of the porphyrin family, the porphyrin(1.0.1.0) called norcorrole (shown in the center of the picture), was detected as an unexpected product of a spontaneous oxidative macrocyclization reaction of the iodidoiron-(III) complex of 2,2′-bidipyrrin. It fills a gap in the family of contracted porphyrinoid variants and shows reactivity consistent with earlier DFT calculations. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5658 / 5660

页数：3

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