Highly Monodisperse MIII-Based soc-MOFs (M = In and Ga) with Cubic and Truncated Cubic Morphologies

被引:140
作者
Pang, Maolin [1 ,2 ,3 ]
Cairns, Amy J. [3 ]
Liu, Yunling [3 ]
Belmabkhout, Youssef [3 ]
Zeng, Hua Chun [1 ,2 ]
Eddaoudi, Mohamed [3 ]
机构
[1] Natl Univ Singapore, Dept Chem & Biomol Engn, Fac Engn, Singapore 117548, Singapore
[2] Natl Univ Singapore, KAUST NUS GCR Program, Fac Engn, Singapore 117548, Singapore
[3] King Abdullah Univ Sci & Technol, Adv Membrane & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia
关键词
METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMER PARTICLES; HYDROGEN STORAGE; ROOM-TEMPERATURE; MODULATION; DANDELIONS; CRYSTALS; GROWTH; SIZE;
D O I
10.1021/ja3049282
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work, we carry out an investigation on shape-controlled growth of In-III- and Ga-III-based square-octahedral metal-organic frameworks (soc-MOFs). In particular, controllable crystal morphological evolution from simple cubes to complex octadecahedra has been achieved, and resultant highly uniform crystal building blocks promise new research opportunities for preparation of self-assembled MOP materials and related applications.
引用
收藏
页码:13176 / 13179
页数:4
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