Markov processes follow from the principle of maximum caliber

被引:30
作者
Ge, Hao [1 ,2 ,3 ,4 ,5 ]
Presse, Steve [6 ]
Ghosh, Kingshuk [7 ]
Dill, Ken A. [8 ]
机构
[1] Peking Univ, Beijing Int Ctr Math Res, Beijing 100871, Peoples R China
[2] Peking Univ, Biodynam Opt Imaging Ctr, Beijing 100871, Peoples R China
[3] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA
[4] Fudan Univ, Sch Math Sci, Shanghai 200433, Peoples R China
[5] Fudan Univ, Ctr Computat Syst Biol, Shanghai 200433, Peoples R China
[6] Univ Calif San Francisco, Dept Pharmaceut Chem, San Francisco, CA 94158 USA
[7] Univ Denver, Dept Phys & Astron, Denver, CO 80208 USA
[8] SUNY Stony Brook, Laufer Ctr Phys & Quantitat Biol, Stony Brook, NY 11794 USA
基金
美国国家卫生研究院;
关键词
STATISTICAL MECHANICS; INFORMATION THEORY; DISTRIBUTIONS; DYNAMICS; ENTROPY;
D O I
10.1063/1.3681941
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Markov models are widely used to describe stochastic dynamics. Here, we show that Markov models follow directly from the dynamical principle of maximum caliber (Max Cal). Max Cal is a method of deriving dynamical models based on maximizing the path entropy subject to dynamical constraints. We give three different cases. First, we show that if constraints (or data) are given in the form of singlet statistics (average occupation probabilities), then maximizing the caliber predicts a time-independent process that is modeled by identical, independently distributed random variables. Second, we show that if constraints are given in the form of sequential pairwise statistics, then maximizing the caliber dictates that the kinetic process will be Markovian with a uniform initial distribution. Third, if the initial distribution is known and is not uniform we show that the only process that maximizes the path entropy is still the Markov process. We give an example of how Max Cal can be used to discriminate between different dynamical models given data. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.3681941]
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页数:5
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