Upgrading a Ti-slag by a roast-leach process

被引:37
作者
Dong, Haigang [1 ,2 ]
Jiang, Tao [1 ]
Guo, Yufeng [1 ]
Chen, Jialin [2 ]
Fan, Xingxiang [2 ]
机构
[1] Cent S Univ, Changsha 410083, Hunan, Peoples R China
[2] Sinoplatinum Met Co Ltd, State Key Lab Adv Technol Comprehens Utilizat Pla, Kunming 650106, Yunnan, Peoples R China
基金
中国国家自然科学基金;
关键词
High Ca and Mg titanium slag; Roasting; Leaching; Synthetic rutile; ROSETTA ILMENITE; TITANIA;
D O I
10.1016/j.hydromet.2011.12.008
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
A roast-acid leaching process has been developed for upgrading titanium slag with high Ca and Mg to a synthetic rutile. The optimized roasting conditions used a Na2CO3 to slag weight ratio of 3:7 at 850 degrees C-900 degrees C for 1 h. The roasted product was mainly comprised of sodium titanate, sodium ferrite and Na-Fe-Ti-O and Na-Mg-Ti-O phases. The impurities associated with the roasted product were leached in water and dilute sulfuric acid solution, while the soluble titanium precipitated as hydrated TiO2. The hydrated TiO2 was transformed into a synthetic rutile, assaying over 95% TiO2 and 0.82% MgO + CaO, by calcination. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:119 / 121
页数:3
相关论文
共 11 条
[1]  
Borowiec K., 1998, US Patent, Patent No. [5,830,420, 5830420]
[2]   Iron Removal and Recovery in the Titanium Dioxide Feedstock and Pigment Industries [J].
Filippou, Dimitrios ;
Hudon, Guillaume .
JOM, 2009, 61 (10) :36-42
[3]  
Gueguin M., 1990, US Patent, Patent No. [4,933,153 A, 4933153]
[4]   Soda ash roasting of titania slag product from Rosetta ilmenite [J].
Lasheen, T. A. .
HYDROMETALLURGY, 2008, 93 (3-4) :124-128
[5]   Chemical benefication of Rosetta ilmenite by direct reduction leaching [J].
Lasheen, TAI .
HYDROMETALLURGY, 2005, 76 (1-2) :123-129
[6]  
Lei T., 2005, Chinese Patent, Patent No. [200,510,048,754.5, 2005100487545]
[7]   Reductive leaching of ilmenite ore in hydrochloric acid for preparation of synthetic rutile [J].
Mahmoud, MHH ;
Afifi, AAI ;
Ibrahim, IA .
HYDROMETALLURGY, 2004, 73 (1-2) :99-109
[8]   An overview on the production of pigment grade titania from titania-rich slag [J].
Sahu, KK ;
Alex, TC ;
Mishra, D ;
Agrawal, A .
WASTE MANAGEMENT & RESEARCH, 2006, 24 (01) :74-79
[9]  
Sun C.H., 2003, Chinese Patent, Patent No. [200,310,110,821.2, 2003101108212]
[10]  
SUN K, 2001, PHYS CHEM EXTRACTING