N,N-Disubstituted-N′-acylthioureas as modular ligands for deposition of transition metal sulfides

被引：14

作者：

Ali, Zahra ^{[1
,2
]}

Richey, Nathaniel E. ^{[1
]}

Bock, Duane C. ^{[1
]}

Abboud, Khalil A. ^{[1
]}

Akhtar, Javeed ^{[3
]}

Sher, Muhammad ^{[2
]}

McElwee-White, Lisa ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[2] Allama Iqbal Open Univ, Dept Chem, Islamabad, Pakistan

[3] MUST, Polymers & Mat Synth Lab PMS, Dept Chem, Alama Iqbal Rd, Mirpur, Azad Kashmir, Pakistan

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 08期

基金：

美国国家科学基金会;

关键词：

CHEMICAL-VAPOR-DEPOSITION; SINGLE-SOURCE PRECURSORS; THIN-FILMS; NICKEL(II) COMPLEXES; CHEMISTRY; AACVD; CHALCOGENIDES; DECOMPOSITION; RHENIUM; COBALT;

D O I：

10.1039/c7dt04860b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

First row transition metal complexes (Ni, Co, Cu, Zn) with N, N-disubstituted-N'-acylthiourea ligands have been synthesized and characterized. Bis(N, N-diisopropyl-N'-cinnamoylthiourea)nickel was found to have the lowest onset temperature for thermal decomposition. Thin film deposition of Ni, Co, and Zn sulfides by aerosol assisted chemical vapor deposition from their respective N, N-diisopropyl-N'-cinnamoylthiourea complexes at 350 degrees C has been demonstrated.

引用

页码：2719 / 2726

页数：8

共 40 条

[1] Deposition of phase pure nickel sulfide thin films from bis(O-alkylxanthato)-nickel(II) complexes by the aerosol assisted chemical vapour deposition (AACVD) method
Akhtar, Masood
Revaprasadu, Neerish
Malik, Mohammad Azad
Raftery, James
[J]. MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2015, 30 : 368 - 375
[2] The influence of precursor on rhenium incorporation into Re-doped MoS2 (Mo1-xRexS2) thin films by aerosol-assisted chemical vapour deposition (AACVD)
Al-Dulaimi, Naktal
Lewis, Edward A.
Savjani, Nicky
McNaughter, Paul D.
Haigh, Sarah J.
Malik, M. Azad
Lewis, David J.
O'Brien, Paul
[J]. JOURNAL OF MATERIALS CHEMISTRY C, 2017, 5 (35) : 9044 - 9052
[3] Pyridine Adducts of Nickel(II) Xanthates as Single-Source Precursors for the Aerosol-Assisted Chemical Vapor Deposition of Nickel Sulfide
Alam, Navee
Hill, Michael S.
Kociok-Koehn, Gabriele
Zeller, Matthias
Mazhar, Muhammad
Molloy, Kieran C.
[J]. CHEMISTRY OF MATERIALS, 2008, 20 (19) : 6157 - 6162
[4] Bismuth(III) dialkyldithiophosphates: Facile single source precursors for the preparation of bismuth sulfide nanorods and bismuth phosphate thin films
Biswal, Jasmine B.
Garje, Shivram S.
Nuwad, Jitendra
Pillai, C. G. S.
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2013, 204 : 348 - 355
[5] Aerosol-Assisted Chemical Vapor Deposition of CdS from Xanthate Single Source Precursors
Buckingham, Mark A.
Catherall, Amanda L.
Hill, Michael S.
Johnson, Andrew L.
Parish, James D.
[J]. CRYSTAL GROWTH & DESIGN, 2017, 17 (02) : 907 - 912
[6] Titanium sulfide thin films from the aerosol-assisted chemical vapour deposition of [Ti(SBut)4]
Carmalt, CJ
O'Neill, SA
Parkin, IP
Peters, ES
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (05) : 830 - 834
[7] Atomic Layer Deposition of Metal Sulfide Materials
Dasgupta, Neil P.
Meng, Xiangbo
Elam, Jeffrey W.
Martinson, Alex B. F.
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (02) : 341 - 348
[8] Some derivatives of benzoyl and furoyl isothiocyanates and their use in synthesizing heterocyclic compounds
Douglass, IB
Dains, FB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1934, 56 : 719 - 721
[9] Thermal behaviors of N-pyrrolidine-N′-(2-chlorobenzoyl)thiourea and its Ni(II), Cu(II), and Co(III) complexes
Emen, Fatih M.
Kulcu, Nevzat
[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2012, 109 (03) : 1321 - 1331
[10] Nanostructured metal chalcogenides: synthesis, modification, and applications in energy conversion and storage devices
Gao, Min-Rui
Xu, Yun-Fei
Jiang, Jun
Yu, Shu-Hong
[J]. CHEMICAL SOCIETY REVIEWS, 2013, 42 (07) : 2986 - 3017

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