Chlorido{N-[(E)-2-(diphenylphosphanyl)benzylidene]-2-(thiophen-2-yl)ethanamine-κP}gold(I)

被引：4

作者：

Chiririwa, Haleden ^{[1
]}

Muller, Alfred ^{[1
]}

机构：

[1] Univ Johannesburg, Dept Chem, Res Ctr Synth & Catalysis, ZA-2006 Johannesburg, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷

基金：

新加坡国家研究基金会;

关键词：

COMPLEXES; AGENTS;

D O I：

10.1107/S1600536811052536

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [AuCl(C(25)H(22)NPS)], crystallizes with two independent molecules in the asymmetric unit in which the thiophene fragments are disordered over two sets of sites with 0.537 (10):0.463 (10) and 0.701 (9):0.299 (9) occupancy ratios. In both cases, the thiophene ring is rotated by approximately 180 degrees for the second component. Important geometrical parameters include Au-P = 2.235 (2) and 2.237 (2) angstrom, Au-Cl = 2.286 (2) and 2.292 (2) angstrom, and P-Au-Cl = 177.39 (8) and 172.63 (7)degrees. Weak intermolecular C-H center dot center dot center dot Cl interactions are observed in the crystal structure.

引用

页码：M49 / +

页数：17

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