Nanostructured hybrid cobalt oxide/copper electrodes of lithium-ion batteries with reversible high-rate capabilities

被引:25
作者
Qi, Yue
Du, Ning [1 ]
Zhang, Hui
Wang, Jiazheng
Yang, Yang
Yang, Deren
机构
[1] Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
关键词
Cobalt oxide; Cu nanorod arrays; Electrodeposition; Rf-sputtering; Anode; Lithium-ion batteries; ELECTROCHEMICAL PROPERTIES; NANOWALL ARRAYS; ANODE MATERIAL; OXIDE; CHALLENGES; BEHAVIOR;
D O I
10.1016/j.jallcom.2012.01.046
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the synthesis of nanostructured hybrid CoO/Cu electrodes through electrodeposition and sputtering. When applied as the anodes for lithium-ion batteries, the CoO/Cu nanowire arrays deliver long cycle life and enhanced power performance than CoO/Cu films. The large accessible surface area and improved electronic/ionic conductivity of the nanostructured electrodes may be responsible for the improved performance. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:83 / 89
页数:7
相关论文
共 33 条
[1]   High rate capability pure Sn-based nano-architectured electrode assembly for rechargeable lithium batteries [J].
Bazin, L. ;
Mitra, S. ;
Taberna, P. L. ;
Poizot, P. ;
Gressier, M. ;
Menu, M. J. ;
Barnabe, A. ;
Simon, P. ;
Tarascon, J. -M. .
JOURNAL OF POWER SOURCES, 2009, 188 (02) :578-582
[2]   Electrochemical and charge/discharge properties of the synthesized cobalt oxide as anode material in Li-ion batteries [J].
Do, Jing-Shan ;
Weng, Chien-Hsiang .
JOURNAL OF POWER SOURCES, 2006, 159 (01) :323-327
[3]   Preparation and characterization of CoO used as anodic material of lithium battery [J].
Do, JS ;
Weng, CH .
JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :482-486
[4]   Porous Co3O4 nanotubes derived from Co4(CO)12 clusters on carbon nanotube templates:: A highly efficient material for Li-battery applications [J].
Du, Ning ;
Zhang, Hui ;
Chen, Bindi ;
Wu, Jianbo ;
Ma, Xiangyang ;
Liu, Zhihong ;
Zhang, Yiqiang ;
Yang, Deren ;
Huang, Xiaohua ;
Tu, Jiangping .
ADVANCED MATERIALS, 2007, 19 (24) :4505-+
[5]   Electrochemical method for direct deposition of nanometric bismuth and its electrochemical properties vs Li [J].
Finke, Alexandre ;
Poizot, Philippe ;
Guery, Claude ;
Dupont, Loic ;
Taberna, Pierre-Louis ;
Simon, Patrice ;
Tarascon, Jean-Marie .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2008, 11 (03) :E5-E9
[6]   Challenges for Rechargeable Li Batteries [J].
Goodenough, John B. ;
Kim, Youngsik .
CHEMISTRY OF MATERIALS, 2010, 22 (03) :587-603
[7]   High-rate, long-life Ni-Sn nanostructured electrodes for lithium-ion batteries [J].
Hassoun, Jusef ;
Panero, Stefania ;
Simon, Patrice ;
Taberna, Pierre Louis ;
Scrosati, Bruno .
ADVANCED MATERIALS, 2007, 19 (12) :1632-+
[8]   Net-structured NiO-C nanocomposite as Li-intercalation electrode material [J].
Huang, X. H. ;
Tu, J. P. ;
Zhang, C. Q. ;
Xiang, J. Y. .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (05) :1180-1184
[9]   Electrochemical properties of NiO/Co-P nanocomposite as anode materials for lithium ion batteries [J].
Huang, X. H. ;
Yuan, Y. F. ;
Wang, Z. ;
Zhang, S. Y. ;
Zhou, F. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (07) :3425-3429
[10]   On the origin of the extra electrochemical capacity displayed by MO/Li cells at low potential [J].
Laruelle, S ;
Grugeon, S ;
Poizot, P ;
Dollé, M ;
Dupont, L ;
Tarascon, JM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (05) :A627-A634