NaCl AS A NOVEL AND GREEN CATALYST FOR THE SYNTHESIS OF BIODYNAMIC SPIRO HETEROCYCLES IN WATER UNDER SONICATION

被引：36

作者：

Dandia, Anshu ^{[1
]}

Jain, Anuj Kumar ^{[1
]}

Bhati, Dharmendra Singh ^{[1
]}

机构：

[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India

来源：

SYNTHETIC COMMUNICATIONS | 2011年 / 41卷 / 19期

关键词：

Green chemistry; multicomponent reaction; ring-closing metathesis; sodium chloride; sonication; FACILE; SPIROOXINDOLES; MALONONITRILE; CONVENIENT; ALKALOIDS; ISATINS;

D O I：

10.1080/00397911.2010.515365

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and novel green catalytic protocol for the synthesis of biologically important spirooxindole derivatives is developed in a one-pot, three-component approach involving substituted isatin, activated methylene reagent, and 3-methyl-1-phenyl-2-pyrazolin-5-one in water under sonication. This report describes the use of sodium chloride as a nonacidic and green catalyst for a variety of substrates. The advantageous features of this methodology are the environmentally benign character, operational simplicity, high yield processing, easy handling, and the fact that the products do not need to be purified.

引用

页码：2905 / 2919

页数：15

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