AgPd@Pd/TiO2 nanocatalyst synthesis by microwave heating in aqueous solution for efficient hydrogen production from formic acid

被引：39

作者：

Hattori, Masashi ^{[1
]}

Shimamoto, Daisuke ^{[2
]}

Ago, Hiroki ^{[1
]}

Tsuji, Masaharu ^{[1
]}

机构：

[1] Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan

[2] Kyushu Univ, Grad Sch Engn Sci, Dept Appl Sci Elect & Mat, Kasuga, Fukuoka 8168580, Japan

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2015年 / 3卷 / 20期

关键词：

ROOM-TEMPERATURE; DECOMPOSITION; GENERATION; CATALYST; AU/C; H2O;

D O I：

10.1039/c5ta01434d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ag100-xPdx/TiO2 (x=7, 10, and 15) catalysts for hydrogen production from formic acid were synthesized in aqueous solution using MW heating. The hydrogen production rate of Ag100-xPdx@Pd/TiO2 increased concomitantly with decreasing x. The best catalytic activity ever reported was obtained for Ag93Pd7@Pd/TiO2 among all heterogeneous catalysts.

引用

页码：10666 / 10670

页数：5

共 12 条

[1] Solar CO2 reduction using H2O by a semiconductor/metal-complex hybrid photocatalyst: enhanced efficiency and demonstration of a wireless system using SrTiO3 photoanodes
Arai, Takeo
Sato, Shunsuke
Kajino, Tsutomu
Morikawa, Takeshi
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (04) : 1274 - 1282
[2] Synthesis and characterization of dendritic and porous Ag-Pd alloy nanostructures
Chen, Limiao
Liu, Younian
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 364 (01) : 100 - 106
[3] VEGARD LAW
DENTON, AR
ASHCROFT, NW
[J]. PHYSICAL REVIEW A, 1991, 43 (06): : 3161 - 3164
[4] Efficient hydrogen production from formic acid using TiO2-supported AgPd@Pd nanocatalysts
Hattori, Masashi
Einaga, Hisahiro
Daio, Takeshi
Tsuji, Masaharu
[J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (08) : 4453 - 4461
[5] Novel PdAu@Au/C Core-Shell Catalyst: Superior Activity and Selectivity in Formic Acid Decomposition for Hydrogen Generation
Huang, Yunjie
Zhou, Xiaochun
Yin, Min
Liu, Changpeng
Xing, Wei
[J]. CHEMISTRY OF MATERIALS, 2010, 22 (18) : 5122 - 5128
[6] The teraton challenge. A review of fixation and transformation of carbon dioxide
Mikkelsen, Mette
Jorgensen, Mikkel
Krebs, Frederik C.
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (01) : 43 - 81
[7] Selective CO2 Conversion to Formate Conjugated with H2O Oxidation Utilizing Semiconductor/Complex Hybrid Photocatalysts
Sato, Shunsuke
Arai, Takeo
Morikawa, Takeshi
Uemura, Keiko
Suzuki, Tomiko M.
Tanaka, Hiromitsu
Kajino, Tsutomu
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (39) : 15240 - 15243
[8] THERMOCHEMICAL ANALYSIS OF PDXAG1-X ALLOYS FROM XPS CORE-LEVEL BINDING-ENERGY SHIFTS
STEINER, P
HUFNER, S
[J]. SOLID STATE COMMUNICATIONS, 1981, 37 (01) : 79 - 81
[9] Tedsree K, 2011, NAT NANOTECHNOL, V6, P302, DOI [10.1038/nnano.2011.42, 10.1038/NNANO.2011.42]
[10] An Efficient CoAuPd/C Catalyst for Hydrogen Generation from Formic Acid at Room Temperature
Wang, Zhi-Li
Yan, Jun-Min
Ping, Yun
Wang, Hong-Li
Zheng, Wei-Tao
Jiang, Qing
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (16) : 4406 - 4409

← 1 2 →