Stepwise synthesis of cellodextrins assisted by a mutant cellulase

被引：22
作者：
Fort, S
Christiansen, L
Schülein, M
Cottaz, S
Driguez, H
机构：
[1] CNRS, Ctr Rech Macromol Vegetales, F-38041 Grenoble 9, France
[2] Novo Nordisk AS, DK-2880 Bagsvaerd, Denmark
来源：
ISRAEL JOURNAL OF CHEMISTRY | 2000年 / 40卷 / 3-4期
关键词：
D O I：
10.1560/5NCY-L9K2-JND4-MB6Q
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A 4(II)-protected alpha -cellobiosyl fluoride is an efficient donor for the enzymatic stepwise condensations onto methyl P-D-glycoside accepters. These reactions, catalyzed by the Cel7B E197A glycosynthase from Humicola insolens, gave cellodextrins from degree of polymerization 3 to 6 in high yields.
引用
收藏
页码：217 / 221
页数：5
相关论文
共 26 条
  • [1] A bifunctionalized fluorogenic tetrasaccharide as a substrate to study cellulases
    Armand, S
    Drouillard, S
    Schulein, M
    Henrissat, B
    Driguez, H
    [J]. JOURNAL OF BIOLOGICAL CHEMISTRY, 1997, 272 (05) : 2709 - 2713
  • [2] ERICKSSON KEL, 1998, ACS S SERIES, V687
  • [3] SELECTIVE CLEAVAGE OF ANOMERIC ACETYL GROUPS OF ACETYLATED GLYCOSYL RESIDUES BY HYDRAZINE
    EXCOFFIER, G
    GAGNAIRE, D
    UTILLE, JP
    [J]. CARBOHYDRATE RESEARCH, 1975, 39 (02) : 368 - 373
  • [4] Isolation, modification, and NMR assignments of a series of cellulose oligomers
    Flugge, LA
    Blank, JT
    Petillo, PA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (31) : 7228 - 7238
  • [5] Highly efficient synthesis of β(1→4)-oligo- and -polysaccharides using a mutant cellulase
    Fort, S
    Boyer, V
    Greffe, L
    Davies, G
    Moroz, O
    Christiansen, L
    Schülein, M
    Cottaz, S
    Driguez, H
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (23) : 5429 - 5437
  • [6] SIMPLE SYNTHESIS OF GLYCOSYL FLUORIDES
    HAYASHI, M
    HASHIMOTO, S
    NOYORI, R
    [J]. CHEMISTRY LETTERS, 1984, (10) : 1747 - 1750
  • [7] HRMOVA M, 2000, 29 INT CARB S HAMB A
  • [8] SYNTHETIC STUDIES ON MUCOPOLYSACCHARIDES .2. DISCRIMINATION BETWEEN THE 2,3-HYDROXYL AND THE 2',3'-HYDROXYL GROUPS OF MALTOSE AND CELLOBIOSE THROUGH THEIR SPECIFIC PROTECTION
    ICHIKAWA, Y
    MANAKA, A
    KUZUHARA, H
    [J]. CARBOHYDRATE RESEARCH, 1985, 138 (01) : 55 - 64
  • [9] NOVEL METHOD FOR POLYSACCHARIDE SYNTHESIS USING AN ENZYME - THE 1ST INVITRO SYNTHESIS OF CELLULOSE VIA A NONBIOSYNTHETIC PATH UTILIZING CELLULASE AS CATALYST
    KOBAYASHI, S
    KASHIWA, K
    KAWASAKI, T
    SHODA, S
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) : 3079 - 3084
  • [10] Glycosynthases: Mutant glycosidases for oligosaccharide synthesis
    Mackenzie, LF
    Wang, QP
    Warren, RAJ
    Withers, SG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (22) : 5583 - 5584
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