Efficient and environmental-friendly dehydration of fructose to 5-hydroxymethyl-2-furfural in water under high pressure of CO2

被引：14
作者：
Motokucho, Suguru [1 ]
Morikawa, Hiroshi [2 ]
Nakatani, Hisayuki [1 ]
Noordover, Bart A. J. [3 ]
机构：
[1] Nagasaki Univ, Chem & Mat Engn Program, 1-14 Bunkyo Machi, Nagasaki 8528521, Japan
[2] Kanagawa Inst Technol, Dept Appl Chem, 1030 Shimo Ogino, Atsugi, Kanagawa 2430292, Japan
[3] Eindhoven Univ Technol, Dept Chem Engn & Chem, POB 513, NL-5600 MB Eindhoven, Netherlands
来源：
TETRAHEDRON LETTERS | 2016年 / 57卷 / 42期
基金：
日本学术振兴会;
关键词：
Biomass; Dehydration reaction; Carbonic acid; Fructose; CO2; CARBON-DIOXIDE; ACID; CONVERSION; INHIBITORS; SOLVENTS; MONOMERS; CATALYST; ZEOLITE; BIOMASS; SYSTEM;
D O I：
10.1016/j.tetlet.2016.09.036
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
To develop reaction systems of chemical conversion of biomass, fructose was heated in an aqueous medium under pressurized CO2, which caused in situ generation of carbonic acid. It gave 5-hydroxymethyl-2-furfural (HMF) as a dehydration product in good yields. The maximum yield of HMF was 92% in the reaction at 90 degrees C under 7.0 MPa of CO2 for 168 h. The reaction proceeded in the absence of any other reagents such as non-volatile acids, organic solvents, inorganic, and organic salts. It means green, environmental friendly, and efficient process was achieved for production of HMF. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4742 / 4745
页数：4
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