Efficient and environmental-friendly dehydration of fructose to 5-hydroxymethyl-2-furfural in water under high pressure of CO2

被引：14

作者：

Motokucho, Suguru ^{[1
]}

Morikawa, Hiroshi ^{[2
]}

Nakatani, Hisayuki ^{[1
]}

Noordover, Bart A. J. ^{[3
]}

机构：

[1] Nagasaki Univ, Chem & Mat Engn Program, 1-14 Bunkyo Machi, Nagasaki 8528521, Japan

[2] Kanagawa Inst Technol, Dept Appl Chem, 1030 Shimo Ogino, Atsugi, Kanagawa 2430292, Japan

[3] Eindhoven Univ Technol, Dept Chem Engn & Chem, POB 513, NL-5600 MB Eindhoven, Netherlands

来源：

TETRAHEDRON LETTERS | 2016年 / 57卷 / 42期

基金：

日本学术振兴会;

关键词：

Biomass; Dehydration reaction; Carbonic acid; Fructose; CO2; CARBON-DIOXIDE; ACID; CONVERSION; INHIBITORS; SOLVENTS; MONOMERS; CATALYST; ZEOLITE; BIOMASS; SYSTEM;

D O I：

10.1016/j.tetlet.2016.09.036

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

To develop reaction systems of chemical conversion of biomass, fructose was heated in an aqueous medium under pressurized CO2, which caused in situ generation of carbonic acid. It gave 5-hydroxymethyl-2-furfural (HMF) as a dehydration product in good yields. The maximum yield of HMF was 92% in the reaction at 90 degrees C under 7.0 MPa of CO2 for 168 h. The reaction proceeded in the absence of any other reagents such as non-volatile acids, organic solvents, inorganic, and organic salts. It means green, environmental friendly, and efficient process was achieved for production of HMF. (C) 2016 Elsevier Ltd. All rights reserved.

引用

收藏

页码：4742 / 4745

页数：4

相关论文

共 37 条

[1] Chain Mobility, Thermal, and Mechanical Properties of Poly(ethylene furanoate) Compared to Poly(ethylene terephthalate) [J].

Burgess, Steven K. ;

Leisen, Johannes E. ;

Kraftschik, Brian E. ;

Mubarak, Christopher R. ;

Kriegel, Robert M. ;

Koros, William J. .

MACROMOLECULES, 2014, 47 (04) :1383-1391

[2] Formation of Tarry Material from 5-HMF in Subcritical and Supercritical Water [J].

Chuntanapum, Athika ;

Matsumura, Yukihiko .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (22) :9837-9846

[3] Alternative Monomers Based on Lignocellulose and Their Use for Polymer Production [J].

Delidovich, Irina ;

Hausoul, Peter J. C. ;

Deng, Li ;

Pfuetzenreuter, Rebecca ;

Rose, Marcus ;

Palkovits, Regina .

CHEMICAL REVIEWS, 2016, 116 (03) :1540-1599

[4] Replacing fossil based PET with biobased PEF; process analysis, energy and GHG balance [J].

Eerhart, A. J. J. E. ;

Faaij, A. P. C. ;

Patel, M. K. .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (04) :6407-6422

[5]

Gandini A, 2008, MONOMERS, POLYMERS AND COMPOSITES FROM RENEWABLE RESOURCES, P115, DOI 10.1016/B978-0-08-045316-3.00006-5

[6] INTRAMOLECULAR C-2-]C-1 HYDROGEN TRANSFER-REACTIONS DURING CONVERSION OF ALDOSES TO 2-FURALDEHYDES [J].

HARRIS, DW ;

FEATHER, MS .

JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (05) :724-725

[7] Lignocellulosic biomass: a sustainable platform for the production of bio-based chemicals and polymers [J].

Isikgor, Furkan H. ;

Becer, C. Remzi .

POLYMER CHEMISTRY, 2015, 6 (25) :4497-4559

[8] Conversion of D-glucose into 5-hydroxymethylfurfural (HMF) using zeolite in [Bmim]Cl or tetrabutylammonium chloride (TBAC)/CrCl2 [J].

Jadhav, Harishandra ;

Taarning, Esben ;

Pedersen, Christian Marcus ;

Bols, Mikael .

TETRAHEDRON LETTERS, 2012, 53 (08) :983-985

[9] DEHYDRATION OF D-FRUCTOSE (FORMATION OF 5-HYDROXYMETHYL-2-FURALDEHYDE AND LEVULINIC ACID) .3. INFLUENCE OF WATER CONCENTRATION ON DEHYDRATION OF D-FRUCTOSE [J].

KUSTER, BFM .

CARBOHYDRATE RESEARCH, 1977, 54 (02) :177-183

[10] 5-lipoxygenase inhibitors with histamine H1 receptor antagonist activity [J].

Lewis, TA ;

Bayless, L ;

Eckman, JB ;

Ellis, JL ;

Grewal, G ;

Libertine, L ;

Nicolas, JM ;

Scannell, RT ;

Wels, BF ;

Wenberg, K ;

Wypij, DM .

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2004, 14 (09) :2265-2268

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