Europium-Doped Y2O3-Coated Diatomite Nanomaterials: Hydrothermal Synthesis, Characterization, Optical Study with Enhanced Photocatalytic Performance

被引:4
作者
Hanifehpour, Younes [1 ]
Abdolmaleki, Mehdi [1 ]
Joo, Sang Woo [2 ]
机构
[1] Sayyed Jamaleddin Asadabadi Univ, Dept Chem, Asadabad 6541861841, Iran
[2] Yeungnam Univ, Sch Mech Engn, Gyongsan 712749, South Korea
基金
新加坡国家研究基金会;
关键词
sono-photocatalytic degradation; europium; diatomite; luminescent; reactive blue 19; ZNO NANOPARTICLES; SONOCATALYTIC DEGRADATION; SONOCHEMICAL SYNTHESIS; Y2O3; NANOPHOSPHORS; DIATOMACEOUS-EARTH; CATALYSTS; SAMARIUM; NANORODS; REMOVAL; WATER;
D O I
10.3390/inorganics9120088
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Eu-doped Y2O3 coated diatomite nanostructures with variable Eu3+ contents were synthesized by a facile hydrothermal technique. The products were characterized by means of energy dispersive X-ray photoelectron spectroscopy (EDX), scanning electron microscopy (SEM), powder X-ray diffraction (PXRD), Brunauer-Emmett-Teller (BET), UV-vis diffuse reflectance spectroscopy, and photoluminescence spectroscopy techniques. As claimed by PXRD, the particles were crystallized excellently and attributed to the cubic phase of Y2O3. The influence of substitution of Eu3+ ions into Y2O3 lattice caused a redshift in the absorbance and a decrease in the bandgap of as-prepared coated compounds. The pore volume and BET specific surface area of Eu-doped Y2O3-coated diatomite is greater than uncoated biosilica. The sonophotocata-lytic activities of as-synthesized specimens were evaluated for the degradation of Reactive Blue 19. The effect of various specifications such as ultrasonic power, catalyst amount, and primary dye concentration was explored.
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页数:19
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